N-Annulation of the BTI Rylene Imide Organic Building Block: Impact on the Optoelectronic Properties of π-Extended Molecular Structures

Colorants Pub Date : 2022-12-30 DOI:10.3390/colorants2010002
J. A. Andrés Castán, S. Abidi, Tatiana Ghanem, S. Touihri, P. Blanchard, G. Welch, Yulian Zagranyarski, J. Boixel, Bright Walker, P. Josse, C. Cabanetos
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引用次数: 1

Abstract

Benzothioxanthene imide (BTI) has recently emerged as an interesting and promising block for organic electronics. In this contribution, we report on the impact of the N-annulation of the latter dye on the optoelectronic of π-extended molecular structures. To do so, the thiophene-diketopyrrolopyrrole was selected, as central π-conjugated core, and either end-capped with two BTIs or its N-annulated version, namely the TCI. While almost similar band gaps were measured for individual rylene imide dyes, significant differences were highlighted, and rationalized, on their π-extended counterparts.
BTI苯乙烯酰亚胺有机构建块的n -环化:对π扩展分子结构光电性能的影响
苯并噻吩酰亚胺(BTI)近年来成为有机电子学中一种有趣且有前途的材料。在这篇文章中,我们报道了后一种染料的n -环化对π扩展分子结构的光电影响。为此,选择噻吩-二酮吡咯作为中心π共轭核,其两端分别有两个bti或其n环化版本,即TCI。虽然几乎相似的带隙测量的个别苯乙烯酰亚胺染料,显着差异被突出,并合理化,在他们的π扩展对应。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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