1,1,1,3,3,3‐Hexafluoro‐2‐propanol

Encyclopedia of Reagents for Organic Synthesis Pub Date : 2010-10-15 DOI:10.1002/047084289X.RN01164

A. Phillips

{"title":"1,1,1,3,3,3‐Hexafluoro‐2‐propanol","authors":"A. Phillips","doi":"10.1002/047084289X.RN01164","DOIUrl":null,"url":null,"abstract":"[920-66-1] C3H2F6O (MW 168.04) \n \nInChI = 1S/C3H2F6O/c4-2(5,6)1(10)3(7,8)9/h1,10H \n \nInChIKey = BYEAHWXPCBROCE-UHFFFAOYSA-N \n \n \n \n \n \n(highly polar, thermally stable, UV transparent solvent that is miscible with water and many polar organic solvents; additive for catalysis applications)1 \n \n \n \nAlternative Names: 1,1,1,3,3,3-hexafluoro-2-hydroxypropane; 1,1,1,3,3,3-hexafluoro-2-propanol; 1,1,1,3,3,3-hexafluoroisopropanol; 1,1,1,3,3,3-hexafluoroisopropyl alcohol; 2,2,2-trifluoro-1-(trifluoromethyl)ethanol; bis(trifluoromethyl)methanol; hexafluoroisopropanol; hexafluoroisopropyl alcohol; HFIP, HFIPA, HFP. \n \n \n \nPhysical Data: bp 58.2 °C/760 mmHg; mp −3.3 °C; d 1.6047 g cm−3; pKa = 9.3.2 \n \n \n \nAnalysis of Reagent Purity: generally used as supplied (>99% technical or >99.97 specialty grade). \n \n \n \nForm Supplied in: water-white liquid; commercially available. \n \n \n \nHandling, Storage, and Precautions: corrosive to eyes on contact and a strong skin and respiratory irritant. May contain traces of 1,1,1,3,3,3-hexafluoroacetone, a potential reproductive hazard. Appropriate precautions should be taken to minimize exposure. \n \n \n \nSolubility: miscible with water and most organic solvents, with the exception of long-chain hydrocarbon solvents.","PeriodicalId":11669,"journal":{"name":"Encyclopedia of Reagents for Organic Synthesis","volume":"1 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2010-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Encyclopedia of Reagents for Organic Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/047084289X.RN01164","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 0

Abstract

[920-66-1] C3H2F6O (MW 168.04) InChI = 1S/C3H2F6O/c4-2(5,6)1(10)3(7,8)9/h1,10H InChIKey = BYEAHWXPCBROCE-UHFFFAOYSA-N (highly polar, thermally stable, UV transparent solvent that is miscible with water and many polar organic solvents; additive for catalysis applications)1 Alternative Names: 1,1,1,3,3,3-hexafluoro-2-hydroxypropane; 1,1,1,3,3,3-hexafluoro-2-propanol; 1,1,1,3,3,3-hexafluoroisopropanol; 1,1,1,3,3,3-hexafluoroisopropyl alcohol; 2,2,2-trifluoro-1-(trifluoromethyl)ethanol; bis(trifluoromethyl)methanol; hexafluoroisopropanol; hexafluoroisopropyl alcohol; HFIP, HFIPA, HFP. Physical Data: bp 58.2 °C/760 mmHg; mp −3.3 °C; d 1.6047 g cm−3; pKa = 9.3.2 Analysis of Reagent Purity: generally used as supplied (>99% technical or >99.97 specialty grade). Form Supplied in: water-white liquid; commercially available. Handling, Storage, and Precautions: corrosive to eyes on contact and a strong skin and respiratory irritant. May contain traces of 1,1,1,3,3,3-hexafluoroacetone, a potential reproductive hazard. Appropriate precautions should be taken to minimize exposure. Solubility: miscible with water and most organic solvents, with the exception of long-chain hydrocarbon solvents.

查看原文本刊更多论文

[920-66-1] c3h2f60 (MW 168.04) InChI = 1S/ c3h2f60 /c4-2(5,6)1(10)3(7,8)9/h1,10H InChIKey = BYEAHWXPCBROCE-UHFFFAOYSA-N(高极性，热稳定，紫外透明的溶剂，与水和许多极性有机溶剂混溶;替代名称:1,1,1,3,3,3-六氟-2-羟基丙烷;1, 1, 1, 3, 3, 3-hexafluoro-2-propanol;1, 1, 1, 3, 3, 3-hexafluoroisopropanol;1, 1, 1, 3, 3, 3-hexafluoroisopropyl酒精;(2, 2, 2-trifluoro-1) - trifluoromethyl乙醇;bis (trifluoromethyl)甲醇;hexafluoroisopropanol;hexafluoroisopropyl酒精;hfipa hfipa hfp物理数据:bp 58.2°C/760 mmHg;mp−3.3°C;D 1.6047 g cm−3;pKa = 9.3.2试剂纯度分析:一般按供应(>99%技术级或>99.97特种级)。供液形式:水白色液体;商业上可用。处理、储存和注意事项:接触对眼睛有腐蚀性，对皮肤和呼吸道有强烈刺激性。可能含有微量1,1,1,3,3,3-六氟丙酮，对生殖有潜在危害。应采取适当的预防措施，尽量减少接触。溶解度:与水和大多数有机溶剂混溶，长链烃溶剂除外。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Encyclopedia of Reagents for Organic Synthesis

自引率

0.00%

发文量