White Light Scanning Interferometry for Nano Surface Metrology

RAN Pub Date : 2017-04-01 DOI:10.11159/icnei17.102
ByoungChang Kim, Tae-Hyung Kim, Sun-Hye Kim, Changkyu Kim, Hyungsuk Lee
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Abstract

Extended Abstract Polymer nanofiber composites for the treatment of hazardous compounds are of considerable scientific and technological interest. In this study, polyamide nanofiber for organic pollutant removal and chemical warfare protection is discussed. The effect of position of functional materials in nanofiber matrix on the photocatalytic activity was studied by comparing the AgTiO2-decorated nylon nanofiber composite (AT-sur-NF) and Ag-TiO2-embedded nylon nanofiber composite (AT-in-NF) [1]. We find that AT-sur-NF shows better photocatalytic activity compared to the photocatalytic activity of AT-in-NF. Based on these results, nylon and meta-aramid nanofibers decorated by various functional nanomaterials were fabricated. The electrospun meta-aramid nanofiber composites exhibit poor chemical stability because of the salt molecules remaining between meta-aramid chains [2]. The chemical stability of meta-aramid nanofiber composites were improved by removing salt molecules during washing and additional thermal treatment. The polyamide nanofiber composites were stacked to enhance mechanical properties and resistivity to chemical warfare agents (CWAs). By controlling the stacking of polyamide nanofiber composites, thickness, weight density, and cool/warm feeling are optimized. In addition, the assemblies exhibit enough resistivity to CWAs while still maintain water vapor transmission to allow evaporation of sweat on the skin. Further study on the thermal properties and microstructure of nylon nanofibers reveals that the chains rigidity and thermal stability increase with decreasing diameter of nylon nanofibers.
纳米表面测量的白光扫描干涉法
高分子纳米纤维复合材料处理有害化合物具有重要的科学和技术意义。本文探讨了聚酰胺纳米纤维在有机污染物去除和化学战防护方面的应用。通过比较agtio2修饰尼龙纳米纤维复合材料(AT-sur-NF)和ag - tio2包埋尼龙纳米纤维复合材料(AT-in-NF)[1],研究了功能材料在纳米纤维基体中的位置对光催化活性的影响。我们发现AT-sur-NF比AT-in-NF具有更好的光催化活性。在此基础上,制备了不同功能纳米材料修饰的尼龙和间芳纶纳米纤维。静电纺间芳纶纳米纤维复合材料的化学稳定性较差,主要是由于盐分子残留在间芳纶链[2]之间。通过去除洗涤过程中的盐分子和额外的热处理,提高了间芳纶纳米纤维复合材料的化学稳定性。通过对聚酰胺纳米纤维复合材料的叠层处理,提高了复合材料的力学性能和抗化学战剂的电阻率。通过控制聚酰胺纳米纤维复合材料的堆叠,优化了材料的厚度、重量密度和冷暖感觉。此外,该组件对cwa具有足够的电阻率,同时仍然保持水蒸气传输,使皮肤上的汗水蒸发。对尼龙纳米纤维的热性能和微观结构的进一步研究表明,随着尼龙纳米纤维直径的减小,链的刚度和热稳定性增加。
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