NANOFIBRAS DE POLI(ÁLCOOL VINÍLICO) COM ÓXIDO DE GRAFENO REDUZIDO PARA APLICAÇÃO EM SENSOR DE GÁS

Beatriz Marques Carvalho, Vitor Hugo Uzeloto Fernandes Mingroni, André Soares da Silva, P. Silva, C. A. Olivati, L. Martins, Luiz Carlos Silva Filho, Deuber Lincon da Silva Agostini
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Abstract

With the advancement of nanotechnology, nanomaterials such as nanofibers have gained attention, as they have applications in technological, environmental and health areas. In this context, electrospinning stands out for being considered a simple and versatile technique that allows the production of nanofibers. Carbon-based additives have been used to compose the polymeric matrix responsible for obtaining nanofibers, such as graphene, which among its applications has been used in gas sensors, as it can detect some molecules, including the ammonia. Thus, it is interesting to carry out studies of the polymer poly(vinyl alcohol) (PVA), together with the additive reduced graphene oxide (rGO), aiming at the application in ammonia gas sensor. Thus, electrospun PVA nanofibers with rGO were produced at different concentrations. To analyze the influence of rGO on PVA nanofibers, they were characterized by optical microscopy (OM) and tested in the presence of ammonia gas, generating graphs of current (i) by time (t). Therefore, electrospun nanofibers with considerable quantity and good formats were obtained, as seen in the OM images. By the graphs of i vs t, it was observed that the nanofibers that contained 4% of rGO showed greater sensitivity in the presence of ammonia gas, proving that rGO can be used as an additive in polymeric nanofibers with application in ammonia gas sensor.
用于气体传感器的还原氧化石墨烯聚乙烯醇纳米纤维
随着纳米技术的发展,纳米纤维等纳米材料在技术、环境和健康等领域的应用日益受到人们的关注。在这种情况下,静电纺丝被认为是一种简单而通用的技术,可以生产纳米纤维。碳基添加剂已被用于组成聚合物基质,用于获得纳米纤维,如石墨烯,其应用之一已用于气体传感器,因为它可以检测一些分子,包括氨。因此,针对聚合物聚乙烯醇(PVA)与添加剂还原氧化石墨烯(rGO)在氨气传感器中的应用进行研究是很有意义的。因此,在不同浓度下制备了含有还原氧化石墨烯的静电纺丝PVA纳米纤维。为了分析还原氧化石墨烯对PVA纳米纤维的影响,我们使用光学显微镜(OM)对其进行了表征,并在氨气存在下进行了测试,生成了电流(i)随时间(t)的图形。因此,如OM图像所示,我们获得了数量可观且格式良好的静电纺纳米纤维。由i / t曲线可知,含有4%还原氧化石墨烯的纳米纤维在氨气存在下表现出更大的灵敏度,证明还原氧化石墨烯可以作为聚合物纳米纤维的添加剂应用于氨气传感器。
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