Synthesis and Electronic Spectra of Some Monoazo Disperse Dyes Derived from N‐Methylindoline

G. Hallas, S. F. Ho
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Abstract

Several monoazo dyes suitable for transfer printing have been prepared from N-methylindoline and compared with the corresponding derivatives of N-methyl -12,3,4-tetrahy-droquinoline (kairoline). The presence of a five-membered terminal ring system leads to diminished π-interaction and results in modest hypsochromic and hypochromic shifts of the visible absorption band, relative to the analogous kairo-line derivatives, together with some deterioration in light-fastness properties on synthetic-polymer fibres.
N -甲基喹啉单偶氮分散染料的合成及电子光谱研究
以n -甲基喹啉为原料制备了几种适合转移印花的单偶氮染料,并与相应的n -甲基-12,3,4-四氢喹啉衍生物进行了比较。五元端环体系的存在导致π相互作用减弱,并导致可见光吸收带相对于类似的凯罗线衍生物出现适度的异色和异色偏移,同时合成聚合物纤维的耐光性也有所下降。
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