Inhibition Effect of Copper Complex of 1-(8-Hydroxy Quinolin-2-yl- Methyl) Thiourea on the Corrosion of Mild Steel in Sodium Chloride Solution

A. Syed, Nasser Abdul, S. Rajendran
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引用次数: 3

Abstract

The Corrosion inhibition of an inhibitor namely Copper complex of 1-(8-hydroxy quinolin-2-yl-methyl) thiourea (Cu-HTF) which controls the corrosion of mild steel immersed in an aqueous solution containing 60 ppm Cl - has been investigated through electrochemical and mass loss method. The formulation consisting of 60 ppm of Cl - and 50 ppm of Cu-HTF offers good inhibition efficiency of 78 %. Polarization study shows that this formulation acts as a cathodic inhibitor.AC impedance spectra indicate that a protective film is formed on the mild steel surface. Fluorescence spectral analysis was used to detect the presence of iron-inhibitor complex. The surface morphology has been analyzed by FTIR, UV-Visible spectroscopy, Scanning Electron Microscope (SEM) and EDAX. Cu-HTF has the ability to prevent the growth of certain microorganisms such as E. coli, Streptococcus, Pseudomonas and Enterobacter.
1-(8-羟基喹啉-2-甲基)硫脲铜配合物对低碳钢在氯化钠溶液中的缓蚀作用
采用电化学和质量损失法研究了1-(8-羟基喹啉-2-酰基甲基)硫脲铜络合物(Cu-HTF)缓蚀剂在60ppm Cl -水溶液中对低碳钢的缓蚀作用。由60 ppm Cl -和50 ppm Cu-HTF组成的配方具有良好的缓蚀效果,缓蚀率为78%。极化研究表明,该配方具有阴极抑制剂的作用。交流阻抗谱表明,在低碳钢表面形成一层保护膜。荧光光谱分析检测铁抑制剂配合物的存在。采用红外光谱(FTIR)、紫外可见光谱(UV-Visible spectroscopy)、扫描电子显微镜(SEM)和EDAX对其表面形貌进行了分析。Cu-HTF有能力阻止某些微生物的生长,如大肠杆菌、链球菌、假单胞菌和肠杆菌。
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