Laju Korosi Logam Baja Karbon Rendah di Larutan Garam pada Berbagai Konsentrasi Inhibitor Korosi dari Ekstrak Daun Pepaya

Ninik Lintang Edi Wahyuni, R. Sihombing, Nurcahyo, Agustinus Ngatin, Y. Sarungu, Alfiana Adhitasari, Bambang Soeswanto, Emma Hermawati Muhari, Retno Indarti
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Abstract

Papaya leaf extract could be used as an organic corrosion inhibitor. Corrosion inhibitors were used as a method to reduce corrosion rate. The most corrosive environment was the marine environment. The purpose of this study was to determine the best concentration of papaya (Carica papaya) leaf extract inhibitor which could reduce the corrosion rate of low carbon steel in a 3.56% NaCl solution environment. The maceration process was carried out for 24 hours with 70% ethanol solvent with a solute:solvent ratio of 1:8 (w/v) at room temperature. Inhibitor extracts were analyzed qualitatively with the phytochemical method. The addition of FeCl3 was carried out on the inhibitor extract from papaya leaves. The color change occurred from blackish brown to greenish black which indicated the presence of tannin compounds in the papaya leaf extract. Corrosion testing was carried out with hot stream temperature setting at 45⁰C to 55⁰C and concentrations of inhibitor extracts at 300, 600, and 900 ppm. The test was conducted for 36 hours with a span of metal mass every 6 hours. Corrosion rate calculation is done by weight loss method. The results showed that papaya leaf extract inhibitors positive contained corrosion inhibitor and could reduce the corrosion rate in 3.56% NaCl solution. The corrosion rate without inhibitor is 1.023 mmpy. Corrosion rates with inhibitor concentrations of 300, 600, and 900 ppm were 0.755, 0.585, and 0.438 mmpy, respectively.
木瓜叶提取物中各种腐蚀性腐蚀性溶液中的金属钢钢腐蚀速率
木瓜叶提取物可作为有机缓蚀剂。采用缓蚀剂作为降低腐蚀速率的方法。最具腐蚀性的环境是海洋环境。在3.56% NaCl溶液环境下,确定木瓜叶提取物缓蚀剂的最佳浓度,以降低低碳钢的腐蚀速率。以70%乙醇为溶剂,溶质:溶剂比为1:8 (w/v),室温浸渍24小时。用植物化学方法对抑制剂提取物进行定性分析。在木瓜叶中添加FeCl3作为抑制剂提取物。木瓜叶的颜色由黑棕色变为绿黑色,表明木瓜叶提取物中含有单宁化合物。腐蚀测试在45⁰C至55⁰C的热流体温度和300、600和900 ppm的抑制剂提取物浓度下进行。试验进行了36小时,每6小时测量一次金属质量。腐蚀速率计算采用失重法。结果表明,番木瓜叶提取物缓蚀剂在3.56% NaCl溶液中具有明显的缓蚀剂作用,可降低腐蚀速率。无缓蚀剂的腐蚀速率为1.023 mmpy。缓蚀剂浓度为300、600和900 ppm时,腐蚀速率分别为0.755、0.585和0.438 mmpy。
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