Pengaruh Transesterifikasi Minyak Kepala Ikan Tuna (Thunnus Albacares) Menggunakan Pereaksi Metanol dan Etanol

Meyffi Merrylin Jacobus, Julius Pontoh, Audy D. Wuntu
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Abstract

Transesterification Fatty acids Tuna (Thunnus albacares) Research on the effect of the transesterification method of tuna fish head oil (Thunnus albacares) using methanol and ethanol reagent has been carried out. The purpose of this study was to determine the effect of methanol and ethanol reagents on the transesterification process. The research methodology used in the transesterification of tuna fish oil (Thunnus albacares) is by using two alkyl source reactants, namely methanol and ethanol where the fatty acid alkyl esters were analyzed by gas chromatography. Transesterification using methanol reagent was carried out with BF3 acid catalyst and ethanol reagent was carried out with alkaline NaOH and KOH catalysts. The results showed that the main fatty acid content in fish oil in tuna's head was DHA, palmitate and linoleic. Transesterification of fish oil using acid (BF3 and methanol) and alkaline (NaOH and ethanol) methods resulted in the slightly different of fatty acid composition. DHA fatty acid has the highest content in ethanol reagent with KOH catalyst, namely (33.55%). Palmitic fatty acid (23.09%) was higher in the ethanol reagent with NaOH catalyst. And linolelaidic fatty acid was higher in transesterification using methanol reagent with BF3 catalyst, namely (20.98%).
金枪鱼头油的转化作用使用甲醇和乙醇
采用甲醇和乙醇试剂对金枪鱼鱼头油进行酯交换反应,研究了酯交换法对金枪鱼鱼头油的影响。本研究的目的是确定甲醇和乙醇试剂对酯交换过程的影响。金枪鱼鱼油酯交换反应的研究方法是采用甲醇和乙醇两种烷基源反应物,用气相色谱法分析脂肪酸烷基酯。用甲醇试剂与BF3酸催化剂进行酯交换,用乙醇试剂与碱性NaOH和KOH催化剂进行酯交换。结果表明,金枪鱼头鱼油中主要脂肪酸含量为DHA、棕榈酸酯和亚油酸。用酸法(BF3和甲醇)和碱法(NaOH和乙醇)对鱼油进行酯交换反应,脂肪酸组成略有不同。以KOH为催化剂的乙醇试剂中DHA脂肪酸含量最高,为(33.55%)。在NaOH催化剂下,棕榈脂肪酸在乙醇试剂中提取率较高,达23.09%。甲醇试剂在BF3催化剂下,亚油酸脂肪酸的酯交换率较高,为20.98%。
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