Modern strategies for repairing transport systems and facilities using modified epoxy plastics

Andrii Buketov, K. Klevtsov, O. Sapronov, O. Sharko, Roman Nehrutsa
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Abstract

The important feature of the ship transportation systems and facilities operation is the possibility of using methods of current and capital repair of machines and mechanisms. The durability of machine parts and elementsoperation significantly depends on the state of the mechanisms at the current moment, the critical conditions of their thermal and power load. This applies especially to engine room components of modern vessels. Based on the above-mentioned problem, the solution of the issue of current repair of transport systems and facilities is important today, since the occurrence of emergency condition while the systems are in operation requires their immediate leveling during the vessels voyage. In this context, the application of modern strategies for the repairing of transport systems and facilities, which involve the use of modified polymer epoxy plastics, is promising. The development of new materials with improved properties is impossible without scientific research of their cohesive characteristics. The latter can be improved by introducing chemically active modifiers into epoxy oligomer. The optimal content of the modifier in the epoxy oligomer was determined in this paper according to the cohesive strength criteria, such as destructive stresses and flexural elastic modulus, impact strength of composites. Epoxy oligomer ED-20 was chosen as the basis for binder formation. Compositions were polymerized with PEPA hardener. 2.4-diaminoazobenzene-4’-carboxylic acid was used as a modifier. It is proved that for the formation of materials with improved cohesive properties, it is necessary to use the composition of the following content: epoxy oligomer ED-20 (100 wt. parts), hardener PEPA (10 wt. parts), modifier 2.4-diaminoazobenzene-4’-carbonate acid (0.5... 1.0 wt. parts). The formation of such material ensures significant increase in the mechanical properties of composites compared to the original epoxy matrix. An important scientific and technical problem regarding the improvement of modern strategies for transport systems and facilities repairing by means of new modified epoxy plastics is solved in this paper. This is achieved by selecting the structural component materials based on the results of the investigations of interphase interaction processes during the formation of heterogeneous systems and their cohesive properties.
使用改性环氧塑料修复运输系统和设施的现代策略
船舶运输系统和设施运行的重要特征是可以使用当前和资本修理机器和机构的方法。机器部件和元件运行的耐久性在很大程度上取决于机构在当前时刻的状态,以及它们的热负荷和功率负荷的临界条件。这尤其适用于现代船舶的机舱部件。基于上述问题,解决当前运输系统和设施的维修问题非常重要,因为系统运行时发生紧急情况,需要在船舶航行期间立即调平。在这方面,应用现代战略修理运输系统和设施,其中包括使用改性聚合物环氧塑料,是有希望的。没有对材料内聚特性的科学研究,就不可能开发出性能改进的新材料。在环氧低聚物中引入化学活性改性剂可以改善环氧低聚物的性能。根据复合材料的破坏应力、弯曲弹性模量、冲击强度等内聚强度指标,确定了改性剂在环氧低聚物中的最佳含量。选择环氧低聚物ED-20作为粘结剂形成的基础。组合物与PEPA固化剂聚合。以2.4-二氨基偶氮苯-4′-羧酸为改性剂。结果表明,为了形成具有改善内聚性能的材料,必须使用以下含量的组成:环氧低聚物ED-20 (100 wt.份),硬化剂PEPA (10 wt.份),改性剂2.4-二氨基偶氮苯-4′-碳酸酯(0.5…1.0 wt. parts)。与原始的环氧基相比,这种材料的形成确保了复合材料机械性能的显著提高。本文解决了利用新型改性环氧塑料改善现代交通系统和设施维修战略的一个重要科学技术问题。这是通过根据异质体系形成过程中相间相互作用过程及其内聚性的研究结果来选择结构组件材料来实现的。
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