Synthesis, Spectral Study of Demi-macrocycles of Ligand N2O2 with Zn (II) Ion

Sameena Rasheed, A. Dwivedi, M. U. Khan
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引用次数: 0

Abstract

Demi-macrocycles have additional sterochemical constrains resulting from the cyclic nature, which depend up on several factors such as macrocyclic ring size, 1-13 number and nature of chelate rings formed on co-ordination influence position of donor and central metal ion Zn(II) provides a number of coordination compounds because of its affinity towards different types of ligands and flexible coordination number ranging from two to eight the filled and shall does not offer crystal field stabilization on Zn(II) in this synthesis Zn(II) complex shows octahedral geometry demi-macrocyclic systems in a template reaction Zn(II) complex has a vitro, antibacterial activities. Zn(II) functions as an antioxidant. It is essential for protein synthesis.
Zn (II)离子配体N2O2半大环的合成与光谱研究
半大环具有额外的体化学约束,这取决于几个因素,如大环的大小,配位上形成的1-13个数和性质的螯合环影响供体和中心金属离子Zn(II)的位置,提供了许多配位化合物,因为它对不同类型配体的亲和力和灵活的配位数范围从2到8,填充和不提供对Zn(II)的晶体场稳定,在这种合成中Zn(II)配合物呈现八面体几何形状的半大环体系在模板反应中Zn(II)配合物具有体外活性。抗菌活性。锌(II)起抗氧化剂的作用。它是蛋白质合成所必需的。
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