Use of Oxygen Scavenger in Well Safety Valve Balancing Operations

M. Lehmann, K. Lepkova, T. Pojtanabuntoeng, Varun Ghodkay, Annamaria Greenwood, Susumu Hirano, Toshiyuki Sunaba
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Abstract

Monoethylene glycol (MEG) is often used to reduce the differential pressure across well valves so that they can be opened without damage. This MEG ultimately commingles with production fluids and if not deoxygenated contributes to the overall content of dissolved oxygen that may be seen by a receiving production facility. Normally, the dissolved oxygen levels would be removed to insignificant levels during fluid transport. Since the corrosion reactions sequester the oxygen as the fluids are exposed to less noble materials of construction, such as carbon steel. However, in facilities that utilise corrosion resistant alloys (CRA) the residual dissolved oxygen level can be so significant that it warrants reduction using oxygen scavengers. This paper reports on corrosion studies that illustrate the consequence of dissolved oxygen levels being carried through to a MEG reclamation unit constructed of CRA, and laboratory and field validation studies on the use of a bisulfite-based scavenger for removal of oxygen in 90wt% MEG used for equalising pressure of Subsurface Safety Valves.
氧气清除剂在油井安全阀平衡作业中的应用
单乙二醇(MEG)通常用于降低井阀之间的压差,使其可以在不损坏的情况下打开。MEG最终与生产流体混合,如果不进行脱氧,则会导致接收生产设备可以看到的溶解氧的总体含量。正常情况下,在流体运输过程中,溶解氧水平会被去除到微不足道的水平。因为当流体暴露在不太贵重的建筑材料(如碳钢)中时,腐蚀反应会隔离氧气。然而,在使用耐腐蚀合金(CRA)的设施中,残余溶解氧水平可能非常显著,因此需要使用除氧剂来降低。本文报告了腐蚀研究,说明了溶解氧水平被带入由CRA建造的MEG回收装置的后果,以及使用亚硫酸盐基清除剂去除用于平衡地下安全阀压力的90wt% MEG中的氧气的实验室和现场验证研究。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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