Degradation of Natural Rubber as Asphalt Mixes Modifier using UV-Ozone Light

Irene I. C. Ritonga, T. Tamrin, M. Marpongahtun
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Abstract

The elastic properties of natural rubber are indispensable in improving the physical properties of asphalt mixtures. However, the long natural rubber molecule chains make it difficult to modify with other polymeric materials, so it needs to be degraded. In this study, the authors succeeded in degrading natural rubber using a combination of UV light and ozone with the addition of an H2O2 initiator; from the FTIR data, it appears that there are peaks indicating vibrations of the C=O and –OH groups indicating that natural rubber chain termination has occurred. The addition of natural rubber to asphalt was carried out with several variations, namely 8; 10; 12; 14; 16 % (to asphalt content), from the results of the softening point and ductility test of the asphalt mixture explained that the addition of 12 % natural rubber was the most optimum mixture. This result explains that efforts to degrade natural rubber using the UV - ozone combination method can increase the optimum insertion of natural rubber into asphalt mixtures by up to 100 % from previous studies.
uv -臭氧光降解天然橡胶作为沥青混合料的改性剂
天然橡胶的弹性性能对改善沥青混合料的物理性能是必不可少的。然而,天然橡胶分子链较长,难以与其他高分子材料进行修饰,因此需要降解。在这项研究中,作者成功地使用紫外光和臭氧的组合,并添加H2O2引发剂来降解天然橡胶;从FTIR数据来看,C=O和-OH基团的振动峰表明发生了天然橡胶链终止。将天然橡胶加入到沥青中进行了几种变化,即8;10;12;14;从沥青混合料的软化点和延性试验结果说明,天然橡胶添加量为12%是最优的混合料。这一结果解释了使用UV -臭氧组合方法降解天然橡胶的努力可以使天然橡胶在沥青混合物中的最佳插入量比以前的研究增加100%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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