Synthesis of nanodispersed titanium dioxide via pH-controlled polymerization of titanium acid

L. Sadovskaya, T. V. Sviridova, M. V. Morozova, D. Sviridov
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Abstract

The possibility of synthesis of highly photoactive nanosized titania employing ion exchange to exert control over polycondensation of titanium acid in aqueous medium has been demonstrated. The resultant spherical TiO2 nanoparticles exhibits extra high light-induced oxidation activity remaining for some time even after termination of UV illumination. The nanodispersed titania readily penetrate into the surface pores and can be used for deposition of photocatalytic coatings by impregnation technique.
ph控制聚合钛酸合成纳米分散二氧化钛
通过离子交换控制钛酸在水介质中的缩聚反应,证明了制备高光活性纳米二氧化钛的可能性。所得的球形TiO2纳米颗粒表现出极高的光诱导氧化活性,即使在紫外线照射结束后仍能保持一段时间。纳米分散二氧化钛易于渗透到表面孔隙中,可通过浸渍技术用于光催化涂层的沉积。
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