{"title":"The polymerization of xylylene bisdialkyl sulfonium salts","authors":"R. A. Wessling","doi":"10.1002/polc.5070720109","DOIUrl":null,"url":null,"abstract":"<p>Paraxylylene bisdialkyl sulfonium salts can be polymerized in several different ways, yielding addition polymers as well as condensation polymers. The chemistry leads to a variety of polymers including poly(<i>p</i>-xylylene), poly(<i>p</i>-xylylidene), poly(xylylene sulfide)s, poly(xylylene oxide)s, and various α-substituted polyxylylenes such as poly(<i>p</i>-xylylene-α-dialkylsulfonium chloride). Addition polymers form via xylylene diradical intermediates. Condensation polymerization can be effected either by coupling with aldehydes or by nucleophilic displacement reactions.</p>","PeriodicalId":16867,"journal":{"name":"Journal of Polymer Science: Polymer Symposia","volume":"72 1","pages":"55-66"},"PeriodicalIF":0.0000,"publicationDate":"1985-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1002/polc.5070720109","citationCount":"128","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Polymer Science: Polymer Symposia","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/polc.5070720109","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 128
Abstract
Paraxylylene bisdialkyl sulfonium salts can be polymerized in several different ways, yielding addition polymers as well as condensation polymers. The chemistry leads to a variety of polymers including poly(p-xylylene), poly(p-xylylidene), poly(xylylene sulfide)s, poly(xylylene oxide)s, and various α-substituted polyxylylenes such as poly(p-xylylene-α-dialkylsulfonium chloride). Addition polymers form via xylylene diradical intermediates. Condensation polymerization can be effected either by coupling with aldehydes or by nucleophilic displacement reactions.
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