Study of Physical Properties of Cadmium Oxide (CdO) and CdO/DNA/RNA Nanostructures Thin Layers Produced by Spray Pyrolysis Technique for Manufacturing Cadmium Oxide (CdO) Nanoparticles and Evaluation of the Effect of DNA/RNA Doping on Their Optical Characteristics

A. Heidari
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引用次数: 11

Abstract

In the current research, Cadmium Oxide (CdO) nanoparticles are produced by ultrasonic waves and the effect of nucleic acids (DNA/RNA) doping on their optical and structural characteristics are investigated. X-ray Diffraction (XRD) analysis confirms extension of peaks and formation of Cadmium Oxide (CdO) nanoparticles. Absorption spectra for the produced samples are shown that addition of DNA/RNA affects the spectrum and absorption edge shifts towards blue region which is due to reduction of nanoparticle size and it confirms by SEM images. In addition, SEM images show the formation of approximately single size ellipsoidal nanostructures for pure Cadmium Oxide (CdO). However, the size, form and distribution of nanoparticles are varied after doping. On the other hand, in the current paper, Cadmium Oxide (CdO) and DNA/RNA/Cadmium Oxide (CdO) nanostructures thin layers are produced using spray pyrolysis technique over a glassy substrate. Annealing of CdO thin layer for half an hour in the air leads to improvement of crystalline structure. Optical characteristics and crystalline structure of samples are studied through X-ray Diffraction (XRD) and UV-Visible spectroscopy. The results of the current study were shown that CdO thin layers are of hexagonal structure. Further, optical gaff of CdO/DNA/RNA/glass thin layer is increased compared to CdO/glass layer.
喷雾热解法制备氧化镉(CdO)及CdO/DNA/RNA纳米结构的物理性质研究及DNA/RNA掺杂对其光学特性的影响
本研究利用超声波制备氧化镉纳米粒子,并研究了核酸(DNA/RNA)掺杂对其光学和结构特性的影响。x射线衍射(XRD)分析证实了氧化镉(CdO)纳米粒子的峰延伸和形成。制备样品的吸收光谱表明,DNA/RNA的加入影响了光谱,吸收边缘向蓝色区域移动,这是由于纳米颗粒尺寸的减小,并且通过SEM图像证实了这一点。此外,扫描电镜图像显示,纯氧化镉(CdO)形成了近似单一尺寸的椭球状纳米结构。然而,掺杂后纳米颗粒的大小、形态和分布都发生了变化。另一方面,在本论文中,使用喷雾热解技术在玻璃基板上制备了氧化镉(CdO)和DNA/RNA/氧化镉(CdO)纳米结构薄层。将CdO薄层在空气中退火半小时后,其晶体结构得到改善。通过x射线衍射(XRD)和紫外可见光谱研究了样品的光学特性和晶体结构。研究结果表明,CdO薄层呈六边形结构。此外,与CdO/玻璃薄层相比,CdO/DNA/RNA/玻璃薄层的光学斜桁增加。
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