Metal-assisted activation of the C–O bond of 2-hydroxyethylmethacrylate. Synthesis and molecular structure of Ti5(OPri)9(µ-OPri)(µ,η2-OC2H4O)(µ3,η2-OC2H4O)3(µ4,η2-OC2H4O)
N. Pajot, R. Papiernik, L. Hubert-Pfalzgraf, J. Vaissermann, S. Parraud
{"title":"Metal-assisted activation of the C–O bond of 2-hydroxyethylmethacrylate. Synthesis and molecular structure of Ti5(OPri)9(µ-OPri)(µ,η2-OC2H4O)(µ3,η2-OC2H4O)3(µ4,η2-OC2H4O)","authors":"N. Pajot, R. Papiernik, L. Hubert-Pfalzgraf, J. Vaissermann, S. Parraud","doi":"10.1039/C39950001817","DOIUrl":null,"url":null,"abstract":"Ti5(OPri)9(µ-OPri)(OC2H4O)5 is formed by the reaction between Ti(OPri)4 and 2-hydroxyethylmethacrylate in toluene at room temperature; the pentanuclear aggregate is asymmetric with the titanium atoms displaying coordination numbers of five, six and seven.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"43 1","pages":"1817-1819"},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"13","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950001817","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 13
Abstract
Ti5(OPri)9(µ-OPri)(OC2H4O)5 is formed by the reaction between Ti(OPri)4 and 2-hydroxyethylmethacrylate in toluene at room temperature; the pentanuclear aggregate is asymmetric with the titanium atoms displaying coordination numbers of five, six and seven.