Synthesis and characterization of iminophosphorane palladacycles

Abstract

: Herein we report on the synthesis and characterization of bisiminophosphoranes as potential tetradentate ligands. Treatment of the latter with palladium acetate gives tetranuclear structures with two ligand moieties linked by acetate-bridging ligands. The addition of ddpm (4 equivalents) provides doubly metallated structures where the phosphine acts as a bidentate chelating ligand.