The Making Processes of Natural Ester from Palm Oil through Transesterification Reaction for Transformer Application

S. Suwarno, Yulia Erina Sari, T. I. D. K. Dewi
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引用次数: 2

Abstract

It has been more than a hundred year since mineral oil was used as liquid insulation for high voltage transformer. Mineral oil is obtained from petroleum through distillation processes. Petroleum is known as non-renewable resources and non-biodegradable. The flash point of mineral oil is around 150°C, thus it creates a problem for high temperature condition. Based on those facts, a new formula of liquid insulation is needed to replace mineral oil. Natural ester oil is derived from vegetable oil. It is biodegradable, non-toxic, non-flammable, and has a higher breakdown voltage. However, the viscosity of vegetable oil is high so that further treatment is needed in order to reduce the viscosity of the oil. This paper reports a sequential procedure in making natural ester oil through transesterification processes using palm oil for transformer application. The alkyl ester can be obtained from the reaction of triglycerides, alcohol and strong base as a catalyst. The by-product, which is glycerol, is then separated from the oil by using gravitational method as its density is higher than the natural ester oil. In this research, methanol is used as a reactant in transesterification reaction due to its cheap price and its fast reactivity. Potassium hydroxide also has a big role in transesterification, its used as a catalyst to make the process easier.
棕榈油酯交换法制备变压器用天然酯的工艺研究
矿物油作为高压变压器的液体绝缘,已有一百多年的历史。矿物油是通过蒸馏过程从石油中获得的。石油是一种不可再生、不可生物降解的资源。矿物油的闪点在150°C左右,因此在高温条件下会产生问题。基于这些事实,需要一种新的液体绝缘配方来取代矿物油。天然酯油是从植物油中提取的。它是可生物降解,无毒,不易燃,并具有较高的击穿电压。然而,植物油的粘度很高,因此需要进一步处理以降低油的粘度。本文报道了以棕榈油为原料,通过酯交换法制备变压器用天然酯油的顺序过程。以甘油三酯、醇和强碱为催化剂反应制得烷基酯。由于其密度高于天然酯油,因此用重力法将副产物甘油从油中分离出来。在本研究中,甲醇因其价格便宜、反应速度快而被用作酯交换反应的反应物。氢氧化钾在酯交换反应中也起着重要作用,它被用作催化剂,使这一过程更容易。
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