Estimation of physical and nonlinear optical parameters of vanadate glasses

ADVANCES IN BASIC SCIENCE (ICABS 2019) Pub Date : 2019-08-29 DOI:10.1063/1.5122378

S. Yadav, S. Kumari, Monika Barala, D. Mohan, R. Dhar, S. Chaudhary

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引用次数: 1

Abstract

Semiconducting Vanadate (V2O5 based) glass has plentiful application in the field of electrochemical batteries and optical switches. Theoretical investigation for density and molar volume are done for semiconducting glass with composition 60V2O5.(40-x) ZnO.xMoO3 (x=10,13,16,19,22). The density decreases from 4.168-4.057g/cm3 with increasing MoO3 content and an opposite behavior is observed for Molar volume. Using Lorentz- Lorenz equation index of refraction is calculated and found to be very high (4.103 to 3.920) and Oxide ion polarizability varies little in the range 2.6935- 2.6908A3. Using generalized Miller’s rule, third order nonlinear optical susceptibility found to be very high 2.39x10−6 to 1.61x10−6 esu. and Nonlinear Index of Refraction varies from 2.194x10−5 to 1.555x10−5esu.Semiconducting Vanadate (V2O5 based) glass has plentiful application in the field of electrochemical batteries and optical switches. Theoretical investigation for density and molar volume are done for semiconducting glass with composition 60V2O5.(40-x) ZnO.xMoO3 (x=10,13,16,19,22). The density decreases from 4.168-4.057g/cm3 with increasing MoO3 content and an opposite behavior is observed for Molar volume. Using Lorentz- Lorenz equation index of refraction is calculated and found to be very high (4.103 to 3.920) and Oxide ion polarizability varies little in the range 2.6935- 2.6908A3. Using generalized Miller’s rule, third order nonlinear optical susceptibility found to be very high 2.39x10−6 to 1.61x10−6 esu. and Nonlinear Index of Refraction varies from 2.194x10−5 to 1.555x10−5esu.

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钒酸盐玻璃物理及非线性光学参数的估计

半导体钒酸盐(V2O5)玻璃在电化学电池和光开关领域有着广泛的应用。对60V2O5.(40-x) ZnO半导体玻璃的密度和摩尔体积进行了理论研究。xMoO3 (x = 10、13、16、19、22)。随着MoO3含量的增加，密度从4.168 ~ 4.057g/cm3下降，而摩尔体积则相反。利用洛伦兹-洛伦兹方程计算了氧化离子的折射率(4.103 ~ 3.920)，在2.6935 ~ 2.6908A3范围内，氧化离子的极化率变化不大。利用广义米勒规则，发现三阶非线性光学磁化率非常高，为2.39x10−6 ~ 1.61x10−6 esu。非线性折射率变化范围为2.194x10−5 ~ 1.555x10−5esu。半导体钒酸盐(V2O5)玻璃在电化学电池和光开关领域有着广泛的应用。对60V2O5.(40-x) ZnO半导体玻璃的密度和摩尔体积进行了理论研究。xMoO3 (x = 10、13、16、19、22)。随着MoO3含量的增加，密度从4.168 ~ 4.057g/cm3下降，而摩尔体积则相反。利用洛伦兹-洛伦兹方程计算了氧化离子的折射率(4.103 ~ 3.920)，在2.6935 ~ 2.6908A3范围内，氧化离子的极化率变化不大。利用广义米勒规则，发现三阶非线性光学磁化率非常高，为2.39x10−6 ~ 1.61x10−6 esu。非线性折射率变化范围为2.194x10−5 ~ 1.555x10−5esu。

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ADVANCES IN BASIC SCIENCE (ICABS 2019)

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