Cure kinetics of a composite friction material with phenolic resin/rubber compounds as organic binder

IF 2.1 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES
Pablo Monreal-Pérez, Laura Ciérvide, Raúl Orzanco, Maite Idareta, Isabel Clavería Ambroj
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引用次数: 2

Abstract

ABSTRACT Cure kinetics of a friction material with different proportions of rubber/resin as organic binders are investigated. The effect of including two different phenolic resins with different B-transformation times is also analysed. An experimental characterisation is done using both a moving die rheometer and an industrial press. Then, predictive models based on Kamal–Sourour, Isayev, and Claxton–Liska equations are defined. Results showed that a higher amount of resin delivered lower induction times and better fitted phenomenological methods. Higher content of resin and resin with lower B-transformation time led to faster curing reactions at laboratory and industrial scales. Samples with no resin presented an induction time that greatly depended on temperature and fitted worse than the models.
以酚醛树脂/橡胶化合物为有机粘结剂的复合摩擦材料的固化动力学
研究了不同比例橡胶/树脂作为有机粘结剂的摩擦材料的固化动力学。还分析了加入两种不同的酚醛树脂和不同的b -转化时间的效果。用移动模流变仪和工业压机进行了实验表征。然后,定义了基于Kamal-Sourour、Isayev和Claxton-Liska方程的预测模型。结果表明,树脂用量越高,诱导次数越少,对现象学方法的拟合效果越好。较高的树脂含量和较短的b -转化时间导致实验室和工业规模的固化反应更快。无树脂样品的诱导时间很大程度上取决于温度,并且比模型拟合更差。
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来源期刊
Plastics, Rubber and Composites
Plastics, Rubber and Composites 工程技术-材料科学:复合
CiteScore
4.10
自引率
0.00%
发文量
24
审稿时长
4 months
期刊介绍: Plastics, Rubber and Composites: Macromolecular Engineering provides an international forum for the publication of original, peer-reviewed research on the macromolecular engineering of polymeric and related materials and polymer matrix composites. Modern polymer processing is increasingly focused on macromolecular engineering: the manipulation of structure at the molecular scale to control properties and fitness for purpose of the final component. Intimately linked to this are the objectives of predicting properties in the context of an optimised design and of establishing robust processing routes and process control systems allowing the desired properties to be achieved reliably.
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