Soft magnetic nanocrystalline materials

Giselher Herzer
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引用次数: 431

Abstract

The microstructure property relationship in soft magnetic nanocrystalline Fe-base materials is surveyed: The basic mechanism is that the magneto-crystalline anisotropy of the small, randomly oriented bcc-Fe grains is averaged out by exchange interaction. The resulting magnetic behaviour can be well described with the random anisotropy model. The latter has been extended to multiphase materials including the case that the grain size exceeds the exchange length and, is able now to describe the hardening mechanism in the overannealed nanocrystalline state due to the precipitation of borides. Further, the crucial role of the coupling mechanism between the grains is discussed. Thus, as a function of temperature, a single sample combines a variety of phenomena ranging from soft, over hard to finally superparamagnetic behaviour. Finally it is shown, how the structural phases present lead to low or vanishing magnetostriction; the random anisotropy effect guarantees an essentially isotropic behaviour comparable to the amorphous case. Together with the suppressed magneto-crystalline anisotropy, the low magnetostriction provides the basis for the superior soft magnetic properties observed in particular compositions.

软磁纳米晶材料
研究了软磁纳米晶铁基材料的微观结构性能关系:其基本机制是通过交换作用平均了小的、随机取向的bcc-Fe晶粒的磁晶各向异性。由此产生的磁性行为可以用随机各向异性模型很好地描述。后者已经扩展到多相材料,包括晶粒尺寸超过交换长度的情况,并且现在能够描述由于硼化物的沉淀而在过退火纳米晶状态下的硬化机制。进一步讨论了晶粒间耦合机制的关键作用。因此,作为温度的函数,单个样品结合了从软、过硬到最终超顺磁行为的各种现象。最后说明了结构相是如何导致低磁致伸缩或消失的;随机各向异性效应保证了与无定形情况相当的本质上的各向同性行为。低磁致伸缩加上抑制的磁晶各向异性,为在特定成分中观察到优越的软磁性能提供了基础。
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