Contribution to the Serbian coal ranking and fly ash characterization using Pb isotopic ratio

Maja B. Đolić, M. Ćujić, Tijana Stanišić, Dragana Čičkarić, M. Ristić, Aleksandra Perić Grujić
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Abstract

The Republic of Serbia generates the majority of its electricity at the thermal power plants (TE) Nikola Tesla, Kolubara, and Kostolac. Coal is extracted from the Kolubara basin, which produces approximately 70% of lignite (an average of 30 million tons per year), and the Kostolac basin, which produces 30% of lignite. Ash, fly ash, and slag are examples of coal combustion residues. Because of the high content of potentially hazardous elements such as As, Pb, Cd, and Cr, environmental pollution with ash and fly ash has been extensively researched. Stable isotopes of lead can be used to trace lead sources. It is possible to monitor the presence, transformation pathways, and environmental impact of Pb by determining its isotopic composition in coal and fly ash. For the first time, the isotopic composition of selected coal samples from the Kolubara and Kostolac mines, as well as fly ash from the Kolubara (A and B), Kostolac (A and B), and Nikola Tesla (TENT A3, A2, B2) thermal power plants, was investigated in this study. The obtained data for 206Pb/207Pb in coal serve as the foundation for ranking domestic coals, whereas the isotopic ratios 206Pb/207Pb and 208Pb/207Pb  in fly ash can be used to monitor and control lead pollution from investigated sources.
铅同位素比对塞尔维亚煤分级和飞灰表征的贡献
塞尔维亚共和国的大部分电力来自尼古拉·特斯拉、科卢巴拉和科斯托拉茨的热电厂。煤炭是从Kolubara盆地和Kostolac盆地提取的,前者生产约70%的褐煤(平均每年3000万吨),后者生产30%的褐煤。煤灰、飞灰和炉渣是煤燃烧残留物的例子。由于粉煤灰中as、Pb、Cd、Cr等潜在有害元素的含量较高,粉煤灰和粉煤灰对环境的污染问题得到了广泛的研究。铅的稳定同位素可以用来追踪铅的来源。通过测定煤和粉煤灰中铅的同位素组成,可以监测铅的存在、转化途径和环境影响。本研究首次对Kolubara和Kostolac煤矿的煤样以及Kolubara (A和B)、Kostolac (A和B)和Nikola Tesla (TENT A3、A2、B2)火电厂的粉煤灰进行了同位素组成研究。获得的煤中206Pb/207Pb数据可作为国内煤的分级依据,而粉煤灰中206Pb/207Pb和208Pb/207Pb同位素比值可用于监测和控制所调查来源的铅污染。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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