Chris L. Hayward , Stephen P. Best , Robin J.H. Clark , Nancy L. Ross , Rob Withnall
{"title":"Polarised single crystal Raman spectroscopy of sinhalite, MgAlBO4","authors":"Chris L. Hayward , Stephen P. Best , Robin J.H. Clark , Nancy L. Ross , Rob Withnall","doi":"10.1016/0584-8539(94)80094-4","DOIUrl":null,"url":null,"abstract":"<div><p>Polarised single-crystal Raman spectra for sinhalite have been collected at 80 K over the range 1300-10 cm<sup>−1</sup>. All 36 of the first-order Raman bands predicted by the factor group analysis (FGA) of the olivine structure type have been observed and assigned. Sinhalite has the smallest unit cell volume of any crystal with the olivine structure and is significantly more distorted than are the silicate olivines. This leads to distortion-related consequences in the vibrational spectra, such as greater wavenumber ranges for each type of mode and reduced Raman intensity for symmetric BO<sub>4</sub> modes. Intense Raman bands in the region 796-468 cm<sup>−1</sup> are assigned to BO<sub>4</sub> rotations/translations which deform the AlO bond without displacement of the aluminium atoms which lie on the M1 sites. Raman-active modes involving M1 cation displacements are incompatible with the FGA.</p></div>","PeriodicalId":82782,"journal":{"name":"Spectrochimica acta. Part A: Molecular spectroscopy","volume":"50 7","pages":"Pages 1287-1294"},"PeriodicalIF":0.0000,"publicationDate":"1994-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0584-8539(94)80094-4","citationCount":"4","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectrochimica acta. Part A: Molecular spectroscopy","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0584853994800944","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 4
Abstract
Polarised single-crystal Raman spectra for sinhalite have been collected at 80 K over the range 1300-10 cm−1. All 36 of the first-order Raman bands predicted by the factor group analysis (FGA) of the olivine structure type have been observed and assigned. Sinhalite has the smallest unit cell volume of any crystal with the olivine structure and is significantly more distorted than are the silicate olivines. This leads to distortion-related consequences in the vibrational spectra, such as greater wavenumber ranges for each type of mode and reduced Raman intensity for symmetric BO4 modes. Intense Raman bands in the region 796-468 cm−1 are assigned to BO4 rotations/translations which deform the AlO bond without displacement of the aluminium atoms which lie on the M1 sites. Raman-active modes involving M1 cation displacements are incompatible with the FGA.
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