Multicomponent adsorption equilibrium of ethylene, propane, propylene and CO2 on 13X zeolite

G. Calleja, A. Jimenez, J. Pau, L. Domínguez, P. Pérez
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引用次数: 55

Abstract

Experimental adsorption isotherms of binary, ternary and quaternary mixtures of ethylene, propane, propylene and CO2 on 13X zeolite have been obtained at 293 K. Experimental data of mixtures were fitted to three theoretical models, the ideal adsorbed solution (IAS), real adsorbed solution (RAS) and spreading pressure dependence (SPD) models to reproduce and predict equilibrium data. With the SPD model, two other temperatures were also studied, 279 and 308 K, in order to calculate the model parameters. The best models for binary and multicomponent mixtures showing the highest deviation from ideality were RAS and SPD, with RAS better than SPD for ternary mixtures.

13X沸石上乙烯、丙烷、丙烯和CO2的多组分吸附平衡
在293 K条件下,得到了乙烯、丙烷、丙烯和CO2的二元、三元和四元混合物在13X沸石上的吸附等温线。将实验数据拟合到理想吸附溶液(IAS)、实际吸附溶液(RAS)和扩散压力依赖(SPD)三种理论模型中,以重现和预测平衡数据。利用SPD模型,还研究了279 K和308 K两个温度,以便计算模型参数。对于二元和多组分混合物的最佳模型是RAS和SPD,其中RAS模型优于SPD模型。
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