Determination of Surface Acidity on The Natural and Synthetic Montmorillonite Clays by Titration Method

S. J. Sekewael
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Abstract

Determination of surface acidity on the natural and synthetic montmorillonite clays has been carried out using the acid-base titration method to count the number of bound acid sites per gram of clay. The total acidity of natural and synthetic montmorillonite surfaces obtained was 4.67 and 5.33 mmol/g, respectively. FTIR analysis results indicate the presence of functional groups from the tetrahedral and octahedral constituents. Both samples have similar absorption patterns. The similarity of absorption patterns was followed by a decrease in intensity and shift in some absorption bands, and the appearance of new absorption bands.
用滴定法测定天然和合成蒙脱土的表面酸度
用酸碱滴定法测定了天然蒙脱土和合成蒙脱土的表面酸度,计算了每克粘土的结合酸位数。所得天然蒙脱土和合成蒙脱土表面的总酸度分别为4.67和5.33 mmol/g。FTIR分析结果表明,四面体和八面体成分中存在官能团。两种样品具有相似的吸收模式。吸收谱图相似后,一些吸收谱带的强度下降和偏移,并出现新的吸收谱带。
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