Size effect of gold nanoparticles on optical and electrical properties of plasmonic silicon solar cell

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
J. Gulomov, R. Aliev, I. Gulomova
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Abstract

One of important tasks of the day is increasing the efficiency and decreasing the cost of the silicon solar cells. There is method of introducing of metal nanoparticles into solar cells to improve its absorption and reduce transmission as well as reflection coefficients. When metal nanoparticles are introduced into silicon solar cell, nanoplasmonic effect will occur. Nanoplasmonic effect lead to modification of light spectrum and generation of extra hot electrons. Nano-plasmonic effect strongly depends on size of nanoparticles. Therefore, in this paper, effect of gold nanoparticles size on properties of silicon solar cell has been studied by using simulation. Gold nanoparticles with sizes of 4 nm, 6 nm, 9 nm, 11 nm and 21 nm have been input into emitter region of silicon solar cell in order to use both of nanoplasmonic-electric and nanoplasmonic-optic effects for enhancing efficiency of silicon solar cell. Open circuit voltage didn't change when size of nanoparticles has been changed from 4 nm to 11 nm. It dropped by 0.017 V when size of nanoparticles was 21 nm. Short circuit current has been maximum 6.7 mA/cm2 at nanoparticle size of 11 nm and minimum 3.1 mA/cm2 at nanoparticle size of 21 nm. It has been found from obtained results that gold nanoparticle with size of 11 nm affected significantly on properties of silicon solar cell. Besides, thickness of silicon solar cell can be decreased without dropping of efficiency by introducing gold nanoparticles. Because, main part of photons is absorbed near to metal nanoparticles inputted region.
金纳米颗粒尺寸对等离子体硅太阳能电池光电性能的影响
当前的重要任务之一是提高硅太阳能电池的效率并降低其成本。有一种方法是将金属纳米粒子引入太阳能电池中,以提高其吸收率,降低透射系数和反射系数。在硅太阳能电池中引入金属纳米粒子,会产生纳米等离子体效应。纳米等离子体效应导致了光谱的改变和超热电子的产生。纳米等离子体效应在很大程度上取决于纳米颗粒的大小。因此,本文采用模拟的方法研究了金纳米颗粒尺寸对硅太阳能电池性能的影响。将尺寸分别为4、6、9、11、21 nm的金纳米粒子注入硅太阳电池发射极区,利用纳米等离子体电效应和纳米等离子体光效应提高硅太阳电池的效率。当纳米颗粒的尺寸从4 nm改变到11 nm时,开路电压没有变化。当纳米颗粒的尺寸为21 nm时,它下降了0.017 V。在纳米颗粒尺寸为11 nm时,短路电流最大为6.7 mA/cm2,在纳米颗粒尺寸为21 nm时,短路电流最小为3.1 mA/cm2。结果表明,尺寸为11 nm的纳米金颗粒对硅太阳能电池的性能有显著影响。此外,引入金纳米粒子可以在不降低效率的情况下减小硅太阳能电池的厚度。由于光子的主要部分在金属纳米粒子输入区附近被吸收。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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