STUDY OF THE CU3AS4TE9-CRASTE3 SECTION OF THE AS2Te3-Cr2Te3-CuTe quasi-ternary system

S. Ismailova
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Abstract

Chemical interactions in the system were studied by methods of physicochemical analysis (DTA, XRD, MSA, determination of density and microhardness) and its phase diagram was constructed. It was found that the phase diagram of the system is a non-quasi-binary section of the quasi-ternary system As2Te3-Cr2Te3-CuTe. At room temperature in the system of solid solutions based on Cu3As4Te9 reaches - 5 mol. % CrAsTe3. The region of the solid solution based on the CrAsTe3 compound has not been established in practice. The dependence of the microhardness and density of alloys of the Cu3As4Te9-CrAsTe3 system on the composition has been investigated.
AS2Te3-Cr2Te3-CuTe准三元体系CU3AS4TE9-CRASTE3截面的研究
采用物化分析(DTA、XRD、MSA、密度测定、显微硬度测定)研究了体系中的化学相互作用,并构建了相图。发现该体系的相图是准三元体系As2Te3-Cr2Te3-CuTe的非准二元部分。在室温下,以Cu3As4Te9为基础的固溶体体系达到- 5 mol. % CrAsTe3。在实践中,以CrAsTe3化合物为基础的固溶体区域尚未确定。研究了Cu3As4Te9-CrAsTe3体系合金显微硬度和密度与组成的关系。
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