PREPARATION AND SWELLING PROPERTIES OF POLY(3,4 –ETHYLENEDIOXYTHIOPHENE)/POLY(ACRYLIC ACID)/BENTONITE COMPOSITE HYDROGELS

K. Hüner
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Abstract

In this study, poly(acrylic acid) (PAA)/bentonite (BNT) composites were synthesized through chemical crosslinking by a chemical polymerization using ammonium persulfate as initiator and N,N’-methylenebisacrylamide as crosslinker. Poly(3,4-ethylenedioxythiophene) (PEDOT) was synthesized by oxidative polymerization and then PEDOT/PAA/BNT composites were prepared by mixing PEDOT at 5%, 10% and 20% by mass into PAA/BNT composite. These hydrogel composites were characterized by FTIR, XRD and SEM. It was observed that water absorbency increased with the increase of PEDOT ratio of hydrogel composites.
聚(3,4 -乙烯二氧噻吩)/聚丙烯酸/膨润土复合水凝胶的制备及溶胀性能
本研究以过硫酸铵为引发剂,N,N′-亚甲基双丙烯酰胺为交联剂,采用化学聚合法制备了聚丙烯酸(PAA)/膨润土(BNT)复合材料。采用氧化聚合法制备了聚(3,4-乙烯二氧噻吩)(PEDOT),并将PEDOT以5%、10%和20%的质量加入到PAA/BNT复合材料中,制备了PEDOT/PAA/BNT复合材料。采用FTIR、XRD和SEM对复合材料进行了表征。结果表明,水凝胶复合材料的吸水率随PEDOT比的增加而增加。
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