E. Azzouyahar, L. Bazzi, M. Essahli, M. Belkhaouda, L. Bammou, A. Lamiri
{"title":"Investigation of the Effect of Natural Extract on Corrosion Behavior of Tin in Na2CO3 Solution","authors":"E. Azzouyahar, L. Bazzi, M. Essahli, M. Belkhaouda, L. Bammou, A. Lamiri","doi":"10.24297/JAC.V5I3.6593","DOIUrl":null,"url":null,"abstract":"The inhibition effect of eugenol oil (EO) on the corrosion of tin in 0.1 M Na 2 CO 3 has been studied by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization technics. The effect of temperature on the corrosion behavior of tin in 0.1 M Na 2 CO 3 with and without addition of eugenol oil was studied in the temperature range 278-308 K. This compound inhibits the corrosion of tin at low concentration. At 4g/L eugenol oil the inhibition efficiency calculated by potentiodynamic polarization and EIS techniques is 70% and 82%, respectively. The inhibition efficiency increased with increase of the inhibitor concentration and decreased with increase of medium temperature. Electrochemical impedance spectroscopy was used to investigate the mechanism of corrosion inhibition. Polarization curves reveal that EO acts as a mixed-type inhibitor in corrosive solution. The results obtained from the different corrosion evaluation techniques are in good agreement.","PeriodicalId":14904,"journal":{"name":"JOURNAL OF ADVANCES IN CHEMISTRY","volume":"30 1","pages":"800-809"},"PeriodicalIF":0.0000,"publicationDate":"2017-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"JOURNAL OF ADVANCES IN CHEMISTRY","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.24297/JAC.V5I3.6593","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The inhibition effect of eugenol oil (EO) on the corrosion of tin in 0.1 M Na 2 CO 3 has been studied by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization technics. The effect of temperature on the corrosion behavior of tin in 0.1 M Na 2 CO 3 with and without addition of eugenol oil was studied in the temperature range 278-308 K. This compound inhibits the corrosion of tin at low concentration. At 4g/L eugenol oil the inhibition efficiency calculated by potentiodynamic polarization and EIS techniques is 70% and 82%, respectively. The inhibition efficiency increased with increase of the inhibitor concentration and decreased with increase of medium temperature. Electrochemical impedance spectroscopy was used to investigate the mechanism of corrosion inhibition. Polarization curves reveal that EO acts as a mixed-type inhibitor in corrosive solution. The results obtained from the different corrosion evaluation techniques are in good agreement.
采用电化学阻抗谱(EIS)和动电位极化技术研究了丁香酚油(EO)对0.1 M na2co3溶液中锡的缓蚀作用。在温度278 ~ 308 K范围内,研究了温度对0.1 M na2co3中添加和不添加丁香酚油时锡腐蚀行为的影响。该化合物能抑制低浓度锡的腐蚀。当丁香酚油浓度为4g/L时,动电位极化法和EIS法的缓蚀率分别为70%和82%。缓蚀效率随缓蚀剂浓度的增加而增加,随介质温度的升高而降低。采用电化学阻抗谱法研究了其缓蚀机理。极化曲线显示EO在腐蚀性溶液中表现为混合型缓蚀剂。不同的腐蚀评价方法得到的结果是一致的。