Beth Rather , Brian Moulton , Michael J. Zaworotko , Florent Perret , Nicole Morel-Desrosiers , Eric Da Silva , Anthony W. Coleman
{"title":"Crystal engineering of a calix-arene dimer embedded in a hydrophobic cavity formed by a diammonium host matrix","authors":"Beth Rather , Brian Moulton , Michael J. Zaworotko , Florent Perret , Nicole Morel-Desrosiers , Eric Da Silva , Anthony W. Coleman","doi":"10.1016/S1463-0184(03)00047-9","DOIUrl":null,"url":null,"abstract":"<div><p>The crystal structure of the 2:1 1,6-diamino-hexane: <em>para</em>-H-calix-4-arene-25,27-di-phosphonate complex shows a designed encapsulation of a calix-arene dimer within a three-dimensional matrix formed by the diamine molecules, the slight mismatch in the length of the diamine molecules compared to the size of the calix-arene molecule is compensated by chain folding in the diamine</p></div>","PeriodicalId":10766,"journal":{"name":"Crystal Engineering","volume":"6 1","pages":"Pages 15-21"},"PeriodicalIF":0.0000,"publicationDate":"2003-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1463-0184(03)00047-9","citationCount":"14","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Crystal Engineering","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1463018403000479","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 14
Abstract
The crystal structure of the 2:1 1,6-diamino-hexane: para-H-calix-4-arene-25,27-di-phosphonate complex shows a designed encapsulation of a calix-arene dimer within a three-dimensional matrix formed by the diamine molecules, the slight mismatch in the length of the diamine molecules compared to the size of the calix-arene molecule is compensated by chain folding in the diamine