Silver Nanowire-based Transparent Electrode as Flexible Anode for Large-Area Organic Light-Emitting Diodes

RAN Pub Date : 2016-04-01 DOI:10.11159/ICNNFC16.118
Minha Kim, Eunji Jung, S. Cho
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Abstract

Extended Abstract Silver nanowire-based transparent electrode was demonstrated as an anode for large-area organic light-emitting diodes (OLEDs). The electrode transparency depends on the density of the silver nanowire network that determines the sheet resistance of the electrode. The trade-off between the transparency and electrical resistance can be circumvented by utilizing an auxiliary silver-grid electrode for developing a large-area flexible electrode with high transparency and low resistance. In order to apply the silver nanowire-based transparent electrode to the anode for OLEDs, the surface roughness should be minimized to reduce the leakage current through the nanometer-thin devices. A roll-to-roll fabrication process was utilized to fabricate a large-area and planarized flexible transparent electrode with silver nanowire and silver auxiliary grid on a polyethylene terephthalate (PET) substrate. The sheet resistance and optical transmittance of the transparent electrode were 5 ohm/square and 90%, respectively. The planarized electrode surface was flat enough to fabricate OLED devices directly on the surface. Due to the scattering effect of the silver nanowire networks, the device efficiency was superior to that fabricated on the conventional ITO glass substrates. Patterned large-area OLED devices were fabricated on the silver nanowire-based transparent anode using a roll-to-roll deposition process. The OLED devices is 10 cm wide and the length is not limited on a 15 cm wide PET roll. The OLED devices were protected with top and bottom moisture barrier layers deposited by an atomic layer deposition method from moisture and oxygen.[1,2] A few technical subjects on the roll-to-roll fabrication processes, emission uniformity, electrode uniformity and surface roughness will be discussed along with a few applications of the large-area flexible OLEDs in the presentation.
银纳米线透明电极作为大面积有机发光二极管柔性阳极
摘要研究了基于银纳米线的透明电极作为大面积有机发光二极管的阳极。电极的透明度取决于银纳米线网络的密度,而银纳米线网络决定了电极的薄片电阻。利用辅助银栅电极开发具有高透明度和低电阻的大面积柔性电极,可以避免透明度和电阻之间的权衡。为了将银纳米线透明电极应用于oled的阳极,必须最小化表面粗糙度,以减少通过纳米薄器件的泄漏电流。采用卷对卷工艺,在聚对苯二甲酸乙二醇酯(PET)衬底上制备了具有银纳米线和银辅助栅格的大面积平面化柔性透明电极。透明电极的片电阻为5欧姆/平方,透过率为90%。平面化的电极表面足够平坦,可以直接在表面上制造OLED器件。由于银纳米线网络的散射效应,器件效率优于传统ITO玻璃基板。采用卷对卷沉积工艺在银纳米线透明阳极上制备了大面积图案OLED器件。OLED器件宽10厘米,长度不受15厘米宽PET卷的限制。通过原子层沉积法沉积的顶部和底部防潮层保护OLED器件免受水分和氧气的侵害。[1,2]本报告将讨论一些关于卷对卷制造工艺、发射均匀性、电极均匀性和表面粗糙度的技术问题,以及大面积柔性oled的一些应用。
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