A convenient preparative method for 1,4-diketones from carboxylic acids

Journal of biochemical toxicology Pub Date : 1977-07-19 DOI:10.1002/JBT.2570270117

S. Watanabe, T. Fujita, K. Suga, Haruhiko Abe

引用次数: 4

Abstract

Various 1,4-diketones were prepared from carboxylic acids via two steps: Grignard reaction with vinylmagnesium chloride and oxidation with Jones reagent catalysed by mercuric propionate. For example, 2,5-undecanedione was prepared from heptanoic acid via 1-undecen-5-one.

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一种由羧酸制备1,4-二酮的简便方法

以羧酸为原料，通过与乙烯基氯化镁的格氏反应和丙酸汞催化的琼斯试剂氧化两步制备了多种1,4-二酮。例如，由庚酸经1-十一烯-5- 1制得2,5-十一烯二酮。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of biochemical toxicology

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