The Residual Characteristic of Chromafenozide and Pyridalyl in Kale

Jung-Hun Sun, Kyu-Won Hwang, K. Jeong, T. Lee, Hyun-Jin Kim, Sang-Jeong Park, J. Moon
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Abstract

BACKGROUND: It is a very important task to block dis-tribution of the agricultural products contaminated with pesticides in advance to protect consumers from residual pesticides among the agricultural products. Therefore, this study was performed to determine residual characteristics of pesticides in time-dependent manner and present scientific evidences for pre-harvest residue limit (PHRL) setting. METHODS AND RESULTS: The tested pesticides, chromafenozide and pyridalyl were sprayed onto the kale twice (seven day intervals) and then the plant samples were collected at 0 (after 3 hours), 1, 2, 3, 5, 7, and 10 days after the last spraying. Residual concentration of chromafenozide in kale decreased with 74.9% (of decreased frac-tion, field 1) and 85.3% (field 2) and pyridalyl decreased with 81.2% (field 1) and 85.8% (field 2), calculated by comparisons of the concentrations at 0 day and 10 days. Also biological half-lives of chromafenozide in kale were 5.6 day (field 1) and 3.4 day (field 2), and those of pyridalyl were 4.3 day (field 1) and 3.5 day (field 2). CONCLUSION(S): If the residues of chromafenozide and pyridalyl in kale from 10 days before harvest are less than 37.6 mg/kg and 58.9 mg/kg, respectively, it is expected that safe kale below MRL can be supplied on the pre-harvest day.
氯硝唑和吡啶在甘蓝中的残留特性
背景:提前阻断被农药污染的农产品配送,保护消费者免受农产品中残留农药的侵害是一项非常重要的任务。因此,本研究旨在确定农药残留特征随时间的变化规律,为采前残留限量(PHRL)的制定提供科学依据。方法与结果:在羽衣甘蓝上喷施2次农药、噻虫肼和吡啶,间隔7 d,于末次喷施后0 (3 h)、1、2、3、5、7、10 d采集植株样品。对照处理第0天和第10天的浓度计算,羽衣甘蓝中噻虫啉残留量分别下降74.9%(田间1)和85.3%(田间2),吡啶残留量分别下降81.2%(田间1)和85.8%(田间2)。甘蓝菜中铬硝唑的生物半衰期分别为5.6 d(田1)和3.4 d(田2),吡啶醇的生物半衰期分别为4.3 d(田1)和3.5 d(田2)。结论(S):如果收获前10天甘蓝菜中铬硝唑和吡啶醇的残留量分别小于37.6 mg/kg和58.9 mg/kg,则可在收获前供应低于MRL的安全甘蓝菜。
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