Influence of acoustic vibrations on the kinetics of liquid-phase chemical reactions involving associates

Abstract

Where γ is some structure-sensitive coefficient and σ changes as σ=Р0sin(2πvt). At the initial stage, the formation of dimmers is governed by the value of k(v)–i. It is almost convenient to create in a reaction system the density fluctuation, uniform in space, at the expense of external periodic force, influencing system an acoustic wave. At the action of a acoustic wave with a frequency v the stretching σ and compression created in system lead to change of kinetic constants k(v)-and destruction of associates. This constant has view: