In-situ Polymerization of Nylon-Cellulose Nano composite

T. Motaung, M. Mochane, Z. L. Linganiso, Ay, A. P. Mashigo
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引用次数: 12

Abstract

Polymeric Nano composite has been strongly studied due to the improvement achieved when a little amount of Nano sized particles are added to the polymer matrix. This is primarily due to large surface area which increased the interaction between the nanoparticles and the polymer. There are different routes for preparation of the polymer Nano composite with Nano fillers it can be melt compound, in-situ polymerization and the solvent method. The in-situ method was found to be best method due to that the nanoparticle is introduced directly to the monomer and it allowed for few minutes to disperse well to the monomer before the initiator is added to start polymerization. The in-situ method gives control over the particle size and morphology. The present studies investigate the surface morphology and thermal properties of nylon when the cellulose Nano-whiskers of different content was added into nylon monomer. SEM for surface studies, TGA for thermal stabilities and FTIR for chemical properties were studied. TGA results reveal that nylon thermal properties changes with addition of Nano crystals compared to pure nylon.
尼龙-纤维素纳米复合材料的原位聚合
聚合物纳米复合材料由于在聚合物基体中加入少量纳米颗粒所取得的改善而得到了广泛的研究。这主要是由于大的表面积增加了纳米颗粒和聚合物之间的相互作用。采用纳米填料制备聚合物纳米复合材料的方法有熔融复合、原位聚合和溶剂法。原位法被认为是最好的方法,因为纳米颗粒被直接引入到单体上,并且在加入引发剂开始聚合之前,它允许几分钟的时间分散到单体上。原位法可以控制颗粒大小和形貌。研究了在尼龙单体中加入不同含量的纤维素纳米晶须对尼龙的表面形貌和热性能的影响。研究了表面形貌的SEM,热稳定性的TGA和化学性质的FTIR。TGA结果表明,与纯尼龙相比,纳米晶体的加入改变了尼龙的热性能。
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