Facile Synthesis of Spinel Nanocrystalline ZnFe2O4: Enhanced Photocatalytic and Microbial Applications

P. Suppuraj, G. Thirunarayanan, M. Swaminathan, I. Muthuvel
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引用次数: 21

Abstract

Abstract Spinel ZnFe2O4 was developed successfully as a heterogeneous-Fenton catalyst for the degradation of Reactive Yellow 86 (RY 86) under UV light. The ZnFe2O4 was characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy (FE-SEM) and UV-diffuse reflectance spectroscopy (UV-DRS). FE-SEM reveals that the some of the particles sizes are in the range from 10 nm to 50 nm. The photocatalytic performance of ZnFe2O4 was evaluated by degradation of RY 86 dye solution under UV light. The degradation rate was highly influenced by pH, initial concentrations of H2O2 and catalyst concentration. The results indicated that ZnFe2O4 could be used as a photocatalyst for treatment of industrial coloured wastewater. The catalyst was reused for five consecutive runs without significant change in its activity. Moreover, the antibacterial effects were investigated.
尖晶石纳米晶ZnFe2O4的快速合成:增强光催化和微生物应用
摘要:制备了尖晶石ZnFe2O4作为紫外光下降解活性黄86 (RY 86)的多相fenton催化剂。采用x射线衍射(XRD)、傅里叶变换红外光谱(FT-IR)、场发射扫描电镜(FE-SEM)和紫外漫反射光谱(UV-DRS)对ZnFe2O4进行了表征。FE-SEM显示,部分颗粒尺寸在10 ~ 50 nm之间。通过紫外光对y86染料溶液的降解,评价了ZnFe2O4的光催化性能。pH、H2O2初始浓度和催化剂浓度对降解率影响较大。结果表明,ZnFe2O4可作为光催化剂用于工业有色废水的处理。催化剂连续重复使用了五次,其活性没有明显变化。并对其抗菌效果进行了研究。
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