Reduction of Sulfur Species in LNG to Ultra Low Levels

N. Ali, Haitham Abdulla, Ahmed Al Ameeri, M. Jacques, Ilhem Kouaiche
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Abstract

ADNOC LNG and TechnipFMC are reviewing options to reduce total sulphur in LNG, from a current realized specification of 4-9 mgS/Nm3, down to less than 1 mgS/Nm3. The requirement is to enhance the quality of the LNG product, and reduce environmental emissions. Several technologies were reviewed, including options to hydrolyze COS present in wet sweet gas, introduction of desulphurization beds downstream the dehydration units, and changing the type of molecular sieves. Those options were extensively reviewed, and found to be inadequate on their own. Therefore, solvent swap within the Acid Gas Removal Unit (AGRU) along with Molecular sieve upgrade was found to be the most viable option. Rigorous efforts were put in place to establish a robust roadmap that serves furnishing the correct basis, defining the required assessments and developing the intended approach and tools. This paper aims to present the overall methodology, approach and efforts undertaken to study the means to reduce sulphur species in LNG, in the present three LNG trains.
将液化天然气中的硫化物降至超低水平
ADNOC LNG和TechnipFMC正在审查减少液化天然气总硫的方案,从目前实现的4-9 mg /Nm3的规格降至低于1 mg /Nm3。要求是提高液化天然气产品的质量,减少环境排放。综述了几种技术,包括水解湿式甜气中COS的选择、在脱水装置下游引入脱硫床以及改变分子筛的类型。对这些备选办法进行了广泛审查,发现它们本身是不够的。因此,在酸性气体去除装置(agu)内进行溶剂交换以及分子筛升级是最可行的选择。严格的工作已经到位,以建立一个健壮的路线图,提供正确的基础,定义所需的评估,并开发预期的方法和工具。本文旨在介绍在目前的三列液化天然气列车中研究减少液化天然气中硫种的总体方法、方法和努力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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