A Battue on Anionic Dye (congo red) Removal from Aqueous Solution of Dye by Acryl amide Grafted Polyethylene

Mst. Sumaia Aktar Sumi, Md. Al Raihan, Md. Wasikur Rahman, Syed Aminul Islam, Dipa Dutta, Fazla Elahi
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Abstract

Polymer modification has drawn much attention in the recent time among which modification by grafting is one of the most selective method. Radiation induced graft polymerization was employed for synthesis of acryl amide grafted polyethylene (AAm-g-PE) adsorbent. Different irradiation doses, monomer concentration and distilled water as a solvent were used to optimize grafting yield. The percentage of Grafting was optimized found to be 383% which was obtained for 6% monomer concentration at 12 kGy radiation dose without initiator in distilled water. The prepared grafted polyethylene was characterized by Fourier Transform Infrared Spectrometer (FTIR). The prepared grafted materials were used to be removed anionic dye (congo red) from aqueous solution of dye. The effectiveness of the adsorbent for removing dye from aqueous solution was evaluated by batch technique. The influences of different experimental parameters on removal process such as contact time and dye concentration were evaluated. Results showed that initial dye concentration of 30 ppm at pH 6.10 yields 65.4% dye removal efficiency by AAm-g-PE film.
丙烯酰胺接枝聚乙烯从染料水溶液中去除阴离子染料刚果红的研究
聚合物的改性是近年来研究的热点之一,其中接枝改性是最具选择性的改性方法之一。采用辐射诱导接枝聚合法制备了丙烯酸酰胺接枝聚乙烯(AAm-g-PE)吸附剂。采用不同的辐照剂量、单体浓度和蒸馏水作为溶剂对接枝率进行优化。在蒸馏水中,单体浓度为6%,辐射剂量为12 kGy,无引发剂,接枝率为383%。用傅里叶变换红外光谱仪(FTIR)对所制备的接枝聚乙烯进行了表征。将所制备的接枝材料用于染料水溶液中阴离子染料(刚果红)的脱除。采用间歇法评价了该吸附剂对水溶液中染料的去除效果。考察了接触时间、染料浓度等不同实验参数对去除过程的影响。结果表明,初始染料浓度为30 ppm, pH为6.10时,AAm-g-PE膜对染料的去除率为65.4%。
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