Synthesis Optimization Of Cathode Precursor Ni0,5 Mn0,4 Co0.1 (OH)2 with Coprecipitation Method

M. Razak, A. Zulfia
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Abstract

The use of conventional fuels such from fossils sourced is non-renewable energy, which makes this energy source less environmentally friendly. The battery that is nowadays used widely is the Lithium-Ion type with variations in the type of electrode. Electrodes have an important role in battery performance, especially at the cathode. Predecessor cathode types such as LiCoO2, LiMnO, and LiNiCo have various disadvantages due to their dangerous nature, insufficient capacity, and poor stability. NMC cathode (NiMnCo), in this case, NMC541 is presented to overcome these deficiencies. The process of making NMC541 cathode can be done by various synthesis methods, one of which is Co-precipitation. The synthesis parameter directly influences the performance of the cathode precursor produced, especially on its microstructure. For that, we try to optimize the synthesis parameters, such as Stirring Speed, and Aging time. The result said that samples with 900 Rpm stirring speed give the best product precursor along to their small size particle and good conductivity. Meanwhile, Aging co-precipitation doesn’t significantly affect coprecipitation precursor products.
共沉淀法合成阴极前驱体Ni0, 5mn0, 4co0.1 (OH)2的优化
使用化石等传统燃料是不可再生能源,这使得这种能源不太环保。目前广泛使用的电池是锂离子电池,电极类型有所不同。电极在电池性能中起着重要的作用,尤其是在阴极。LiCoO2、LiMnO、LiNiCo等之前的阴极类型由于性质危险、容量不足、稳定性差等缺点而存在诸多弊端。NMC阴极(NiMnCo),在这种情况下,提出了NMC541来克服这些缺陷。制备NMC541阴极的方法有多种,共沉淀法是其中一种。合成参数直接影响阴极前驱体的性能,尤其是其微观结构。为此,我们尝试优化合成参数,如搅拌速度和时效时间。结果表明,搅拌速度为900转/分的样品具有颗粒小、导电性好等优点。时效共析出对共析出前体产物影响不显著。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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