Synthesis of Silica from Rice Husk Waste for Hydrophobic Material as an Anti-Water Coating for Eyeglasses

P. Z. Nehan, Ahmad Ali Akbar Akbar, Muhammad Ilham Nur Karim, Raychan Abyqa Fahriza, M. Zainuri
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Abstract

: Hydrophobic materials made of silica as a coating for glasses are very attractive. The synthesis of silica (SiO 2 ) from rice husk ash was successfully carried out using the sol-gel method. The hydrophobic silica composition is made with four variations of silica, consisting of 0.5, 1.0, 1.5, 2.0 g and polydimethylsiloxane (PDMS) keep constant in 20 g. The raw material was first characterized by X-ray Fluorescence (XRF) to investigate element composition. Then, silica powder obtained from rice husk ash was characterized by Fourier Transform Infrared Spectroscopy (FTIR), Particle Size Analyzer (PSA) and Water Contac Angel (WCA) were employed to investigate functional groups material, size of particles and hydrophobicity of the prepared samples for coating glass. The result of contact angel from coating glass exhibited more than 90 ◦ and the maximum hydrophobicity properties of polydimethylsiloxane/silica (PDMS/SiO 2 ) was about 111.40 ◦ for the silica composition of 2 g.
稻壳废二氧化硅制备眼镜防水涂层用疏水材料
由二氧化硅制成的疏水材料作为玻璃涂层非常有吸引力。以稻壳灰为原料,采用溶胶-凝胶法制备了二氧化硅。疏水二氧化硅组合物由4种不同的二氧化硅组成,分别为0.5、1.0、1.5、2.0 g,聚二甲基硅氧烷(PDMS)保持恒定在20 g。首先用x射线荧光(XRF)对原料进行了表征,以研究其元素组成。利用傅里叶变换红外光谱(FTIR)、粒度分析仪(PSA)和水接触角(WCA)对稻壳灰制备的二氧化硅粉体进行了表征,并对制备的涂层玻璃样品的官能团、粒径和疏水性进行了表征。涂层玻璃的接触角大于90◦,当二氧化硅组分为2 g时,聚二甲基硅氧烷/二氧化硅(PDMS/ sio2)的最大疏水性约为111.40◦。
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