I. W. Sutapa, Dwi Astuti Kasmanto, Rosmawaty, M. Maahury
{"title":"Biodiesel cracking process from beef tallow using catalyst bentonite intercalated NiCl2","authors":"I. W. Sutapa, Dwi Astuti Kasmanto, Rosmawaty, M. Maahury","doi":"10.1063/5.0059518","DOIUrl":null,"url":null,"abstract":"Biodiesel cracking from beef tallow is a method to produce biogasoline. The biodiesel from beef tallow obtain by esterification and transesterification reaction. The cracking process will produce biogasoline with carbon chain lengths that are lighter (C4−C12). In this study the cracking process is done using bentonite intercalated NiCl2 catalyst to shorten the time and the use of high temperatures. Production of bentonite NiCl2-intercalated catalyst calcined at a temperature of 600 °C for 2 hours and characterized using SEM. A cracking temperature was conducted at 450 °C and 500 °C, then the product characterized using GC-MS. The chromatogram’s result showed the presence of new compounds. The new compounds are methyl formate (C5H10O2); methyl undecanoate (C12H24O2); 1,3-propanediol (C5H12O2); nonanoic acid (C11H22O2), and 1,2-dioxolane (C10H20O2).","PeriodicalId":13712,"journal":{"name":"INTERNATIONAL CONFERENCE ON ENERGY AND ENVIRONMENT (ICEE 2021)","volume":"47 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2021-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"INTERNATIONAL CONFERENCE ON ENERGY AND ENVIRONMENT (ICEE 2021)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1063/5.0059518","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 2
Abstract
Biodiesel cracking from beef tallow is a method to produce biogasoline. The biodiesel from beef tallow obtain by esterification and transesterification reaction. The cracking process will produce biogasoline with carbon chain lengths that are lighter (C4−C12). In this study the cracking process is done using bentonite intercalated NiCl2 catalyst to shorten the time and the use of high temperatures. Production of bentonite NiCl2-intercalated catalyst calcined at a temperature of 600 °C for 2 hours and characterized using SEM. A cracking temperature was conducted at 450 °C and 500 °C, then the product characterized using GC-MS. The chromatogram’s result showed the presence of new compounds. The new compounds are methyl formate (C5H10O2); methyl undecanoate (C12H24O2); 1,3-propanediol (C5H12O2); nonanoic acid (C11H22O2), and 1,2-dioxolane (C10H20O2).