Gwenaëlle Rousse , Calin Wurm , Mathieu Morcrette , Juan Rodriguez-Carvajal , Joël Gaubicher , Christian Masquelier
{"title":"Crystal structure of a new vanadium(IV) diphosphate: VP2O7, prepared by lithium extraction from LiVP2O7","authors":"Gwenaëlle Rousse , Calin Wurm , Mathieu Morcrette , Juan Rodriguez-Carvajal , Joël Gaubicher , Christian Masquelier","doi":"10.1016/S1466-6049(01)00092-7","DOIUrl":null,"url":null,"abstract":"<div><p>A new vanadium(IV) diphosphate, VP<sub>2</sub>O<sub>7</sub>, was obtained by lithium extraction from LiVP<sub>2</sub>O<sub>7</sub>. The parent compound, LiVP<sub>2</sub>O<sub>7</sub>, is built on [P<sub>2</sub>O<sub>7</sub>] groups and [VO<sub>6</sub>] octahedra and its structure has been confirmed by Synchrotron X-ray powder diffraction. The extraction of one lithium, both electrochemically or chemically, leads to VP<sub>2</sub>O<sub>7</sub><span> which presents a totally different diffraction pattern diagram. The crystal structure of this new compound was determined from Synchrotron X-ray powder diffraction on the chemically prepared sample. The framework of LiVP</span><sub>2</sub>O<sub>7</sub> is maintained upon lithium extraction, and VP<sub>2</sub>O<sub>7</sub> crystallizes in space group <em>P2<sub>1</sub></em>. Compared to LiVP<sub>2</sub>O<sub>7</sub>, there is a very large cell distortion due to a modification of the shape of the tunnels that contained lithium ions along with an oxidation of the vanadium V<sup>III</sup> to V<sup>IV</sup> that induces shorter V–O bond lengths. The phase transformation from LiVP<sub>2</sub>O<sub>7</sub> to VP<sub>2</sub>O<sub>7</sub> is found to be displacive and not reconstructive.</p></div>","PeriodicalId":100700,"journal":{"name":"International Journal of Inorganic Materials","volume":"3 7","pages":"Pages 881-887"},"PeriodicalIF":0.0000,"publicationDate":"2001-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1466-6049(01)00092-7","citationCount":"27","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Inorganic Materials","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1466604901000927","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 27
Abstract
A new vanadium(IV) diphosphate, VP2O7, was obtained by lithium extraction from LiVP2O7. The parent compound, LiVP2O7, is built on [P2O7] groups and [VO6] octahedra and its structure has been confirmed by Synchrotron X-ray powder diffraction. The extraction of one lithium, both electrochemically or chemically, leads to VP2O7 which presents a totally different diffraction pattern diagram. The crystal structure of this new compound was determined from Synchrotron X-ray powder diffraction on the chemically prepared sample. The framework of LiVP2O7 is maintained upon lithium extraction, and VP2O7 crystallizes in space group P21. Compared to LiVP2O7, there is a very large cell distortion due to a modification of the shape of the tunnels that contained lithium ions along with an oxidation of the vanadium VIII to VIV that induces shorter V–O bond lengths. The phase transformation from LiVP2O7 to VP2O7 is found to be displacive and not reconstructive.