THERMAL CARACTERIZATION OF SOYBEAN AND GRAPE SEED OIL-BASED POLYMERS: NEW SYNTHESIS PATHWAY FOLLOWING GREEN CHEMISTRY’S PRINCIPLES

M. V. D. Almeida, R. Alarcon, G. Bannach
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Abstract

Abstract This paper describes the synthesis of polymers from glycerol and vegetable oils as soybean and grape seed, synthesized following the principles of green chemistry.  Simultaneous thermogravimetric analysis – differential thermal analysis (TG-DTA) and differential scanning calorimetry (DSC) were employed to evaluate the thermal decomposition, thermal stability, and oxidation, glass transition and crystallization processes. Hence it was possible to verify that they have glass transition near to room temperature. Therefore these polymers may be used as chemical slow release agents triggered by temperature and as thermal security tags. Trabalho SiAT 13 CARACTERIZACAO TERMICA DE POLIMEROS DE OLEO DE SOJA E UVA SINTETIZADO POR NOVA ROTA SINTETICA SEGUINDO PRINCIPIOS DA QUIMICA VERDE. Trabalho apresentado no VII SiAT – Simposio de Analise de Termica realizado no periodo de 19 a 21 de julho de 2015 em Bauru, na Faculdade de Ciencias – UNESP.
大豆和葡萄籽油基聚合物的热表征:遵循绿色化学原理的新合成途径
摘要本文以大豆籽、葡萄籽等植物油为原料,根据绿色化学原理合成了甘油聚合物。同时采用热重分析-差热分析(TG-DTA)和差示扫描量热法(DSC)来评估热分解、热稳定性、氧化、玻璃化转变和结晶过程。因此,有可能验证它们在接近室温时发生玻璃化转变。因此,这些聚合物可用作温度触发的化学缓释剂和热安全标签。中国科学院学报,2013年,中国科学院院士,中国科学院院士,中国科学院院士,中国科学院院士,中国科学院院士,中国科学院院士。2015年7月21日,在巴黎,联合国科学大学科学学院。
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