Role of Micro-nano Hexagonal Boron Nitride Coordination on Thermal Conductivity and Breakdown Strength of Epoxy Composites

Zhuolin Cheng, Jiao Xiang, Chuang Zhang, Hang Fu, L. Xin, Xiaotong Zhang, Shihang Wang, Jianying Li
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Abstract

Epoxy resin (EP) has been used as insulating material in power electronic transformer (PET), while low thermal conductivity of EP limits the heat dissipation efficiency of PET. Role of Micro-nano hexagonal boron nitride coordination on thermal conductivity and breakdown strength of epoxy composites was explored. A thermal conductivity of 0.544 W/(m·K) was obtained for 10 wt% BN/EP micro composites, increased by 149.5% compared with pristine epoxy. In addition, the specimen with a dual doping of 10 wt% h-BN and 5 wt% nano filler exhibited both improved thermal conductivity of 0.527 W/(m·K) and breakdown strength of 118.3 kV/mm. It is found that micro-BN could effectively increase the thermal conductivity since efficient heat transform path would be built inside epoxy matrix. Meanwhile, nano-BN would bring in independent interfacial regions that capture carriers at low filler content. Based on the coordination of micro-nano particles, the thermal conductivity and breakdown strength can thus be enhanced simultaneously.
微纳六方氮化硼配位对环氧复合材料导热性能和击穿强度的影响
环氧树脂(EP)作为绝缘材料被广泛应用于电力电子变压器(PET)中,但EP的低导热系数限制了PET的散热效率。探讨了微纳六方氮化硼配位对环氧复合材料导热性能和击穿强度的影响。10 wt% BN/EP微复合材料的导热系数为0.544 W/(m·K),比原始环氧树脂提高了149.5%。此外,双掺杂10 wt% h-BN和5 wt%纳米填料的试样的导热系数提高了0.527 W/(m·K),击穿强度提高了118.3 kV/mm。结果表明,微氮化硼在环氧树脂基体内部形成了有效的热传导通道,可以有效地提高环氧树脂的导热系数。同时,纳米bn会带来独立的界面区域,在低填料含量下捕获载流子。基于微纳粒子的配位,可以同时提高导热性和击穿强度。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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