Effect of Different Concentrations of Titanium Oxide (TiO2) Addition on the Crystallization Behaviour and Some Properties of Alkaline Earth Aluminosilicate Glass-Ceramics

Abstract

Glass-ceramics in the CaO-MgO-Al2O3-SiO2 quaternary base glass system was produced via melting technique using feldspar, limestone and magnesite as sources of starting materials. Glass-ceramics production involves making a base glass, annealing and cooling to room temperature and then reheating the base glass to nucleation and crystal growth temperatures. Characterization of the produced glass-ceramics was carried out using a scanning electron microscope (SEM). The effects of the crystallization process on some properties such as hardness, chemical durability in acid and alkali media of samples were determined. The results portrayed that glass-ceramic samples to which various amounts of TiO2 (2,4,6,8 and 10 wt.%) were incorporated showed the formation of crystalline phases dispersed in the matrix of their respective residual glassy phases. Significant improvement in hardness, as well as minimum weight loss, were recorded for all the glass-ceramic samples. On the contrary, the glass samples did not crystallize despite subjecting them to heat treatment, their hardness values were low and they were not resistant to acid (1M HCl) and alkali (1M NaOH) attacks. The inability of TiO2 addition to fully transform them into glass-ceramics remains a shortcoming. However, the glass-ceramic samples obtained from this study can be used for tiling works.