Electrospinning Preparation of PAN/TiO2 Nanofibers and Photocatalytic Regeneration Properties for Methylene Blue dye

Ali K. Abdullah, Farah M. Radee, Widad S. Hanoosh
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Abstract

The nanofiber membranes prepared by electrospinning method attracted the attention of researchers in the field of pollutant treatment due to their ease of manufacture, efficient performance and ease of removal. Some of these membranes lack the possibility of reuse due to low efficiency and high regeneration cost. In this paper, we were able to prepare nanofiber membranes from polyacrylonitrile (PAN) and PAN/TiO2 by adding different ratios (5,10 and 15) wt% of TiO2 respectively. The resultants nanofibers were characterized using Field Emission Scanning microscope (SEM), Fourier Transform Infrared spectroscopy (FTIR). These prepared membranes enable effective and complete degradation of MB dye in water using ultraviolet (UV) irradiation with the possibility of reuse and high efficiency after washing with distilled water. The efficiency is up to 98% when 15wt% TiO2 was used, while the degradation reaches to 83% when reused the nanofibers composite (PAN/TiO2). The work not only explains the possibility of using and reusing nanofiber films in the treatment of pollutants but also gives a detailed of understanding the behavior of the membrane in dye degradation.
静电纺丝制备PAN/TiO2纳米纤维及其对亚甲基蓝染料的光催化再生性能
静电纺丝法制备的纳米纤维膜因其制备方便、性能高效、易于去除等优点,引起了污染物处理领域研究人员的广泛关注。其中一些膜由于效率低、再生成本高而缺乏再利用的可能性。在本文中,我们可以通过添加不同比例(5、10和15)wt%的TiO2,分别从聚丙烯腈(PAN)和PAN/TiO2制备纳米纤维膜。利用场发射扫描显微镜(SEM)、傅里叶红外光谱(FTIR)对合成的纳米纤维进行了表征。这些制备的膜能够在紫外线(UV)照射下有效和完全地降解水中的MB染料,并且在蒸馏水洗涤后具有重复使用的可能性和高效率。当TiO2用量为15wt%时,降解效率可达98%,而当PAN/TiO2复合材料重复使用时,降解率可达83%。这项工作不仅解释了纳米纤维膜在污染物处理中使用和再利用的可能性,而且还详细了解了纳米纤维膜在染料降解中的行为。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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