Case History of Dehydration-Technology Improvement for HCPF Production in the Daqing Oil Field

Zhihua Wang, Xinyu Lin, Tianyu Yu, Zhiwei Hu, Mengmeng Xu, Hongtao Yu
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引用次数: 5

Abstract

ally defined as a permanent permeability reduction after the HPAM solution flows through the porous media), a water-phase velocity, and a lower mobility ratio between the water and oil phases (Wu et al. 2012; Zhang et al. 2015). All these allow higher oil recovery from the larger reservoir volume swept and higher oil-displacement efficiency with polymer fluids. Evidence from pilot tests in the Daqing oil field clearly demonstrates the feasibility and superiority of the HCPF method, which is worth pursuing (Yang et al. 2006b; Denney 2009; Zhu et al. 2013). Yang et al. (2006a) also used high-concentration HPAM solution to conduct flooding studies for a Canadian oil field and illustrated the promising effect of HPAM, showing that it can increase the recovery factor to 21% of original oil in place (OOIP), even though, during the process of HCPF, the oil/water mixture is more easily emulsified and is separated with more difficulty because more HPAM is produced with the liquid. Emulsifications are ubiquitous in oil-production operations, and they are often responsible for oil-productivity impairment and increased production costs associated with transportation and separation, which are more serious in the HCPF process. Emulsions formed without addition of particles or chemicals might be stabilized by polar components in the crude oil such as resins and asphaltenes. Numerous publications have reported that a number of factors could impact the emulsion stability. McLean and Kilpatrick (1997) studied the role of asphaltenes and their interactions with the resins and surrounding crude media in forming interfacial films leading to emulsion stability. Grutters et al. (2007) observed that polar resins, such as naphthenic acids, play an important role in stabilizing the emulsions. Liu et al. (2002) used zeta-potential measurements to study the interaction between bitumen and clay in aqueous solutions. Yang et al. (2007) studied the stability of paraffin/water emulsions, and they argued that the adsorption of particles at interfaces may be controlled by adjusting the electrostatic interaction between particles and the interface without changing hydrophobicity, which is thought to be a main controlling factor of emulsion type and stability. Wang and Alvarado (2008) sampled aqueous phase and oil from a Wyoming reservoir and studied the effect of salinity and pH on emulsion stability. The role of polymer is to further provide stabilization conditions for emulsions, leading to more-complex emulsification behavior. Rigidity of the water/oil interface has been attributed to significant contributions to the suppression of films, hence limiting coalescence. In other words, the rigidity of the surface that is reflected by the rheology is not controlled by interfacial tension in these stable emulsions. At the same time, significant effort has been dedicated to designing protocols to break up harmful emulsions in oil production (Kokal 2005; Nasiri et al. 2013; Liu et al. 2014). Many dehydration methods, such as gravity sedimentation, centrifugation, vacuum heating, adsorption, and electro-demulsification, are available for emulsified oil in the petroleum industry (Mohammed et al. 1994; Sun et al. 1999; Eow and Ghadiri 2002; Jin and Wojtanowicz 2013). Electro-demulsification technology has been applied extensively to separate oil and water in emulsified oil because it is regarded as the best method in terms of high Copyright © 2016 Society of Petroleum Engineers
大庆油田HCPF生产脱水工艺改进实例
(通常定义为HPAM溶液流过多孔介质后的永久性渗透率降低)、水相速度以及水与油相之间较低的迁移率(Wu et al. 2012;Zhang et al. 2015)。所有这些都可以从更大的油藏体积中获得更高的采收率,并提高聚合物流体的驱油效率。大庆油田中试的证据清楚地证明了HCPF方法的可行性和优越性,值得进一步推广(Yang et al. 2006b;Denney 2009;Zhu et al. 2013)。Yang等人(2006a)也使用高浓度HPAM溶液对加拿大某油田进行了驱油研究,证明了HPAM具有良好的驱油效果,尽管在HCPF过程中,由于液体中产生了更多的HPAM,油水混合物更容易乳化,分离难度更大,但HPAM可以将采收率提高到原油的21% (OOIP)。乳化现象在石油生产过程中无处不在,它们通常会导致产油能力下降,并增加与运输和分离相关的生产成本,这在HCPF过程中更为严重。在不添加颗粒或化学物质的情况下形成的乳剂可能会被原油中的极性成分(如树脂和沥青质)稳定下来。许多出版物报道了许多因素可能影响乳液的稳定性。McLean和Kilpatrick(1997)研究了沥青质的作用及其与树脂和周围粗介质的相互作用,在形成导致乳液稳定性的界面膜中的作用。Grutters等人(2007)观察到极性树脂,如环烷酸,在稳定乳剂方面起着重要作用。Liu et al.(2002)使用ζ电位测量来研究沥青和粘土在水溶液中的相互作用。Yang等(2007)对石蜡/水乳液的稳定性进行了研究,认为在不改变疏水性的情况下,可以通过调节颗粒与界面之间的静电相互作用来控制颗粒在界面处的吸附,疏水性被认为是乳液类型和稳定性的主要控制因素。Wang和Alvarado(2008)从怀俄明州的一个油藏中取样水相和油,研究了盐度和pH值对乳状液稳定性的影响。聚合物的作用是进一步为乳液提供稳定条件,导致更复杂的乳化行为。水/油界面的刚性归因于抑制薄膜的显著贡献,从而限制了聚并。换句话说,在这些稳定的乳液中,由流变性反映的表面刚性不受界面张力的控制。与此同时,人们还致力于设计在石油生产过程中分解有害乳剂的方案(Kokal 2005;Nasiri et al. 2013;Liu et al. 2014)。许多脱水方法,如重力沉降、离心、真空加热、吸附和电破乳,可用于石油工业中的乳化油(Mohammed et al. 1994;Sun et al. 1999;Eow and Ghadiri 2002;Jin and Wojtanowicz 2013)。电破乳技术在乳化油中分离油水方面得到了广泛的应用,因为电破乳技术被认为是高收率的最佳方法©2016年美国石油工程师学会
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