Lokesh Bettada, Mounesh, K. Chandrakala, K.M. Sateesha, M. Amshumali, L. K. Sannegowda, A. Lagashetty
{"title":"A Novel Approach for Electrochemical Sensing of 2-Amino-4-methylphenol Using Magnetic Polypyrrole as a Sensing Platform","authors":"Lokesh Bettada, Mounesh, K. Chandrakala, K.M. Sateesha, M. Amshumali, L. K. Sannegowda, A. Lagashetty","doi":"10.1080/22297928.2023.2170278","DOIUrl":null,"url":null,"abstract":"Abstract A core-shell structured magnetic nano-composite Fe3O4@PPy, synthesized by the chemical oxidative method and the electrochemical behavior of the composite assessed under different conditions. The modified Fe3O4@PPy/GC electrode employed to determine the 2-aminophenol (2AMP) by cyclic voltammetry (CV), differential pulse voltammetry (DPV), and chrono-amperometry (CA). 2AMP exhibited cathodic peak on the Fe3O4@PPy/GC electrode. The linear response observed for 2AMP in the concentration range (50 to 450 nM; CV, 50 to 450 nM; DPV and 50-300 nM; in amperometry). The limit of detection (CV; 15nmol L-1, DPV; 16.5 nmol L-1 and 4 nmol L-1 in amperometry) with a limit of quantification (CV; 45 nmol L-1, DPV; 49.5 nmol L-1 and up to 50nmol L-1 in amperometry), respectively, on the modified electrode. GRAPHICAL ABSTRACT","PeriodicalId":7793,"journal":{"name":"Analytical Chemistry Letters","volume":"124 1","pages":"28 - 38"},"PeriodicalIF":0.0000,"publicationDate":"2023-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analytical Chemistry Letters","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/22297928.2023.2170278","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Abstract A core-shell structured magnetic nano-composite Fe3O4@PPy, synthesized by the chemical oxidative method and the electrochemical behavior of the composite assessed under different conditions. The modified Fe3O4@PPy/GC electrode employed to determine the 2-aminophenol (2AMP) by cyclic voltammetry (CV), differential pulse voltammetry (DPV), and chrono-amperometry (CA). 2AMP exhibited cathodic peak on the Fe3O4@PPy/GC electrode. The linear response observed for 2AMP in the concentration range (50 to 450 nM; CV, 50 to 450 nM; DPV and 50-300 nM; in amperometry). The limit of detection (CV; 15nmol L-1, DPV; 16.5 nmol L-1 and 4 nmol L-1 in amperometry) with a limit of quantification (CV; 45 nmol L-1, DPV; 49.5 nmol L-1 and up to 50nmol L-1 in amperometry), respectively, on the modified electrode. GRAPHICAL ABSTRACT