A Novel Approach for Electrochemical Sensing of 2-Amino-4-methylphenol Using Magnetic Polypyrrole as a Sensing Platform

Lokesh Bettada, Mounesh, K. Chandrakala, K.M. Sateesha, M. Amshumali, L. K. Sannegowda, A. Lagashetty
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引用次数: 0

Abstract

Abstract A core-shell structured magnetic nano-composite Fe3O4@PPy, synthesized by the chemical oxidative method and the electrochemical behavior of the composite assessed under different conditions. The modified Fe3O4@PPy/GC electrode employed to determine the 2-aminophenol (2AMP) by cyclic voltammetry (CV), differential pulse voltammetry (DPV), and chrono-amperometry (CA). 2AMP exhibited cathodic peak on the Fe3O4@PPy/GC electrode. The linear response observed for 2AMP in the concentration range (50 to 450 nM; CV, 50 to 450 nM; DPV and 50-300 nM; in amperometry). The limit of detection (CV; 15nmol L-1, DPV; 16.5 nmol L-1 and 4 nmol L-1 in amperometry) with a limit of quantification (CV; 45 nmol L-1, DPV; 49.5 nmol L-1 and up to 50nmol L-1 in amperometry), respectively, on the modified electrode. GRAPHICAL ABSTRACT
磁性聚吡咯作为传感平台的2-氨基-4-甲基苯酚电化学传感新方法
摘要:采用化学氧化法合成了核壳结构磁性纳米复合材料Fe3O4@PPy,并对复合材料在不同条件下的电化学行为进行了评价。改进后的Fe3O4@PPy/GC电极采用循环伏安法(CV)、差分脉冲伏安法(DPV)和计时安培法(CA)测定2-氨基酚(2AMP)。2AMP在Fe3O4@PPy/GC电极上呈现出阴极峰。2AMP在浓度范围(50 ~ 450 nM)内的线性响应;CV, 50 ~ 450 nM;DPV和50-300 nM;在电流滴定法)。检出限(CV;15nmol L-1, DPV;16.5 nmol L-1和4 nmol L-1(安培法),定量极限(CV;45 nmol L-1, DPV;分别为49.5 nmol L-1和高达50nmol L-1(安培)。图形抽象
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CiteScore
2.30
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0.00%
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