Effects of Organic and Inorganic Colloids on Iodine Mobilization in Groundwater of the Datong Basin, Northern China

Kun Qian, Junxia Li, Xianjun Xie, Yijun Yang
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引用次数: 1

Abstract

In order to identify the effects of groundwater colloids on iodine mobilization in aquifer system, nine groundwater samples were in-situ filtered through successive pore-sized membranes (0.45 μm, 30 kDa and 5 kDa) using filtration technique under N2 atmosphere. Obvious decrease in groundwater iodine, Fe, Al and DOC was observed in the larger pore-sized fractions, indicating that groundwater iodine is closely associated with larger Fe-Al colloids. The analysis result of sample DT15-27 suggests that the extremely reducing condition could promote iodine dissolved in the truly dissolved phase. For low iodine groundwater, no good correlation between iodine and Fe, Al, DOC was observed for all sequential filtration steps, suggesting that groundwater iodine is trapped in the truly dissolved phase because of competitive adsorption of iron/aluminum.

有机和无机胶体对大同盆地地下水碘运移的影响
为了研究地下水胶体对含水层系统中碘运移的影响,在N2气氛下,采用过滤技术对9个地下水样品分别通过0.45 μm、30 kDa和5 kDa孔径的连续膜进行原位过滤。地下水碘、Fe、Al和DOC在较大孔径组分中明显降低,说明地下水碘与较大的Fe-Al胶体密切相关。样品DT15-27的分析结果表明,极还原条件能促进碘在真溶相中溶解。对于低碘地下水,在所有顺序过滤步骤中,碘与Fe、Al、DOC之间没有很好的相关性,表明地下水碘由于铁/铝的竞争吸附而被困在真正的溶解相中。
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