A KINETIC STUDY OF ESTERIFICATION OF NAPHTHENIC ACIDS FROM A COLOMBIAN HEAVY CRUDE OIL

Abstract

This article presents the kinetic study of the esterification reaction of naphthenic acids from a Colombian heavy crude oil, with a Total Acid Number (TAN) of 7,33 mgKOH/g, in a batch type reactor. Temperature was changed between 150 - 250°C while the ratio moles of methanol per mole of carboxylic groups, remained constant in 20:1. The reaction time was varied from 0 - 600 minutes. Reduction in the concentration of naphthenic acids in the reactor is determined by the measurement of Number Total Acid (TAN), ASTM D 664. Naphthenic acids were extracted from the crude and structurally characterized by Fourier Transform Infrared Spectroscopy (FTIR), Nuclear Magnetic Resonance (NMR) and Gel Permeation Chromatography (GPC).